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NAPHTHACENE

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NAPHTHACENE Basic information

Product Name:
NAPHTHACENE
Synonyms:
  • TETRACENE
  • NAPHTHACENE
  • NAPHTHYCENE
  • 2,3-Benzanthrene
  • Chrysogen
  • Methacene
  • Rubene
  • Tetracen
CAS:
92-24-0
MF:
C18H12
MW:
228.29
EINECS:
202-138-9
Product Categories:
  • Light Emitters and Dopants
  • Sublimed Materials
  • Acceptor Materials
  • Arenes
  • Building Blocks
  • Chemical Synthesis
  • Donor Materials
  • Donor-Acceptor Materials
  • Materials Science
  • OLED and PLED Materials
  • Organic and Printed Electronics
  • Organic Building Blocks
  • Organic Field Effect Transistor (OFET) Materials
  • Organic Photovoltaic (OPV) Materials
  • Aromatic Hydrocarbons (substituted) & Derivatives
  • OTFT/OFET/OPV Materials
  • p-Type Organic Semiconductors
  • p-Type Small Molecules
Mol File:
92-24-0.mol
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NAPHTHACENE Chemical Properties

Melting point:
>300 °C(lit.)
Boiling point:
305.1°C (rough estimate)
Density 
1.35
refractive index 
1.5500 (estimate)
form 
Crystalline Powder
color 
Orange
Water Solubility 
1.507ug/L(25 ºC)
Merck 
14,6369
BRN 
1909299
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
92-24-0(CAS DataBase Reference)
EPA Substance Registry System
Naphthacene (92-24-0)
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Safety Information

Hazard Codes 
Xn,N
Risk Statements 
40-50/53
Safety Statements 
45-36/37-61-60-24/25
RIDADR 
UN 3077 9/PG 3
WGK Germany 
3
RTECS 
QI7605000
HS Code 
29029090

MSDS

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NAPHTHACENE Usage And Synthesis

Chemical Properties

orange powder

Uses

p-Type organic conductor and OLED dopant. Sublimed grade for organic electronic device applications.

Uses

Naphthacene is a polycyclic aromatic hydrocarbon. Naphthacene is often used as a molecular organic semiconductor in organic field-effect transistors and organic light-emitting diodes. Naphthacene is also used in various applications involving the enhancement of photocurrent.

Uses

Naphthacene is a polycyclic aromatic hydrocarbon. Naphthacene is often used as a molecular organic semiconductor in organic field-effect transistors and organic light-emitting diodes. Naphthacene is a lso used in various applications involving the enhancement of photocurrent.

Definition

ChEBI: An acene that consists of four ortho-fused benzene rings in a rectilinear arrangement.

General Description

Benz[b]anthracene is an ethylnylated acene that is a conducting polymer, which can be used as a donor material. It has a high photoluminescence and quantum yield that makes it a promising candidate in the development of single crystal electronic material.

Hazard

Explodes when shocked, reacts with oxidizing materials.

Purification Methods

Naphthacene crystallises in orange needles from EtOH, *C6H6 or toluene. Dissolve it in sodium-dried *benzene and pass it through a column of alumina. The eluent is evaporated under vacuum, and the chromatography is repeated using fresh *benzene. Finally, the naphthacene is sublimed in vacuo at 186o. [Martin & Ubblehode J Chem Soc 4948 1961, UV: Clar Chem Ber 65 517 1932, Clar Chem Ber 69 607 1936, IR: Cannon & Sutherland Spectrochim Acta 4 373 1951, Beilstein 5 H 718, 5 IV 2545.]

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