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2-Bromo-4-methylaniline

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2-Bromo-4-methylaniline Basic information

Product Name:
2-Bromo-4-methylaniline
Synonyms:
  • 2-bromo-4-methyl-benzenamin
  • 2-Bromo-4-methylbenzenamine
  • 2-Bromo-4-toluidine
  • 2-bromo-p-toluidin
  • 2-Bromo-4-methylaniline,99% (4-Amino-3-bromtoluol)
  • 2-Bromo-p-toluid
  • 4-Amino-3-bromotoluene~2-Bromo-p-toluidine
  • 2-Bromo-4-methylanline
CAS:
583-68-6
MF:
C7H8BrN
MW:
186.05
EINECS:
209-515-7
Product Categories:
  • Aromatic Hydrocarbons (substituted) & Derivatives
  • Anilines, Amides & Amines
  • Amines
  • blocks
  • Bromides
  • Bromine Compounds
Mol File:
583-68-6.mol
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2-Bromo-4-methylaniline Chemical Properties

Melting point:
14-16 °C (lit.)
Boiling point:
240 °C (lit.)
Density 
1.5 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.602(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Chloroform (Slightly)
form 
Oil
pka
2.97±0.10(Predicted)
color 
Dark Yellow to Dark Beige
Specific Gravity
1.500
Water Solubility 
Insoluble in water.
BRN 
1931711
Stability:
Air Sensitive
InChIKey
UVRRJILIXQAAFK-UHFFFAOYSA-N
CAS DataBase Reference
583-68-6(CAS DataBase Reference)
NIST Chemistry Reference
Benzenamine, 2-bromo-4-methyl-(583-68-6)
EPA Substance Registry System
Benzenamine, 2-bromo-4-methyl- (583-68-6)
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Safety Information

Hazard Codes 
T,Xi,Hazard
Risk Statements 
23/24/25-36/37/38-33-20/21/22
Safety Statements 
36/37/39-45-26
RIDADR 
UN 2810 6.1/PG 3
WGK Germany 
3
RTECS 
XU4300000
Hazard Note 
Irritant/Toxic
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29214300

MSDS

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2-Bromo-4-methylaniline Usage And Synthesis

Chemical Properties

clear light yellow to brown liquid

Uses

2-Bromo-4-methylaniline has been used in the synthesis of iminophosphoranes.

General Description

2-Bromo-4-methylaniline participates in palladium catalyzed selective amination of 3-bromoquinoline to yield 3-(2-bromo-4-methylphenylamino) quinoline. It reacts with ethyl and methyl imidazo[1,2-a]pyridine-2-carboxylates in the presence of Me3Al to form amide.

2-Bromo-4-methylaniline Preparation Products And Raw materials

Preparation Products

Raw materials

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