(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties

form 

crystal

color 

red-orange

Water Solubility 

insoluble

Sensitive 

air sensitive

CAS DataBase Reference

210057-23-1(CAS DataBase Reference)

Safety Information

Risk Statements 

36/37/38

Safety Statements 

24/25

WGK Germany 

3

HS Code 

29310099

MSDS

• Language:English Provider:ACROS

(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Usage And Synthesis

Reactions

1. The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
2. Forms superior catalysts for asymmetric reductive aminations.
3. Catalyst used for the asymmetric hydrogenation of enol phosphonates.
4. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
5. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
6. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
7. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
8. Palladium catalyzed asymmetric phosphination.

(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate(210057-23-1)Related Product Information

• Xylene
• Benzene
• 1,3-CYCLOOCTADIENE
• Rhodium
• (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
• 1,2-BIS(PHOSPHINO)BENZENE
• (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE
• (-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
• (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene,98+%(S,S)-Me-DUPHOS,(+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE
• (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE,(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane,98+%(R,R)-Me-BPE
• (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
• (R,R,R,R)-2,3-BIS(2,5-DIMETHYL-PHOSPHOLANYL)BENZO[B]THIOPHENE CYCLOOCTADIENE RHODIUM(I) TETRAFLUOROBORATE COMPLEX
• 2,3-Bis[(2R,5R)-2,5-dimethylphospholano]-N-(3,5-dimethylphenyl)maleimide
• 2,3-Bis[(2R,5R)-2,5-dimethylphospholano]-N-benzylmaleimide(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
• (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
• (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)trifluoromethanesulfonate
• (-)-2,3-Bis[(2R,5R)-2,5-dimethylphospholano]maleic anhydride(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
• 1,2-Bis[(2R,5R)-2,5-dimethylphospholano]-3,3,4,4-tetrafluoro-1-cyclobutene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate