3-VINYLPHENYLBORONIC ACID Chemical Properties

Melting point:

141-147 °C

Boiling point:

320.2±35.0 °C(Predicted)

Density 

1.09±0.1 g/cm3(Predicted)

storage temp. 

2-8°C

form 

powder or crystals

pka

8.34±0.10(Predicted)

BRN 

3030426

CAS DataBase Reference

15016-43-0(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi,Xn

Risk Statements 

36/37/38-22

Safety Statements 

26-36-37/39

RIDADR 

UN 2811 6.1/PG 3

WGK Germany 

3

Hazard Note 

Irritant

HS Code 

2931900090

MSDS

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3-VINYLPHENYLBORONIC ACID Usage And Synthesis

Uses

suzuki reaction

Uses

Reactant involved in:

• Suzuki-Miyaura reactions
• Molecular imprinting of fructose and pinacol
• Synthesis of arylmercapturic acids via Chen-Lam-Evans arylation
• Three-component cross-coupling yeilding diarylketones
• Generation of acyl anion equivalents

General Description

May contain varying amounts of anhydride.

Purification Methods

This binder for paper or glass crystallises in white plates from H2O (m 144-145o), and its IR has max 919 and 995 (CH2CH=CH2), 1350 (B-O) and 3220 (OH) cm-1 . The dibromo derivative crystallises in white needles from H2O with m 196-197.5o. [Wesley & Rush J Org Chem 27 2598 1962, Beilstein 16 III 1279, 16 IV 1677.]

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