Basic information Safety Supplier Related

Bis(4-chlorobenzyl) azodicarboxylate

Basic information Safety Supplier Related

Bis(4-chlorobenzyl) azodicarboxylate Basic information

Product Name:
Bis(4-chlorobenzyl) azodicarboxylate
Synonyms:
  • N-[(4-chlorophenyl)methoxy-oxomethyl]iminocarbamic acid (4-chlorophenyl)methyl ester
  • DCAD Bis(4-chlorobenzyl) azodicarboxylate
  • (4-chlorophenyl)methyl (NE)-N-[(4-chlorophenyl)methoxycarbonylimino]carbamate
  • Di-p-chlorobenzyl azodicarboxylate(DCAD)
  • Bis(4-chlorobenzyl) azodicarboxylate
  • Bis(4-chlorobenzyl) azodicarboxyle
  • (E)-bis(4-chlorobenzyl) diazene-1,2-dicarboxylate
  • Di-(4-chlorobenzyl)azodicarboxylate≥ 98%(HPLC)
CAS:
916320-82-6
MF:
C16H12Cl2N2O4
MW:
367.18
Mol File:
916320-82-6.mol
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Bis(4-chlorobenzyl) azodicarboxylate Chemical Properties

Melting point:
108-112°C
Boiling point:
505.6±45.0 °C(Predicted)
Density 
1.36±0.1 g/cm3(Predicted)
storage temp. 
2-8°C, protect from light
form 
solid
Appearance
White to yellow Solid
InChI
InChI=1S/C16H12Cl2N2O4/c17-13-5-1-11(2-6-13)9-23-15(21)19-20-16(22)24-10-12-3-7-14(18)8-4-12/h1-8H,9-10H2
InChIKey
UIFGGABIJBWRMG-UHFFFAOYSA-N
SMILES
N(C(OCC1=CC=C(Cl)C=C1)=O)=NC(OCC1=CC=C(Cl)C=C1)=O
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Safety Information

Hazard Codes 
Xi
Risk Statements 
43
Safety Statements 
36/37
WGK Germany 
3
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Bis(4-chlorobenzyl) azodicarboxylate Usage And Synthesis

Chemical Properties

White crystals

Uses

Reactant for preparation of:

  • Amino thioesters via guanidine-catalyzed biomimetic enantioselective decarboxylative Mannich and amination reactions of malonic acid half thioesters
  • Hydroacylation reaction of aldehydes in Ionic liquid (IL) medium
  • DCAD (di-p-chlorobenzyl azodicarboxylate) for Mitsunobu coupling reactions

General Description

Learn More at the Professor and Product Portal of Professor Bruce Lipshutz.

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