Basic information Uses Safety Supplier Related
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1,4-Benzoquinone dioxime

Basic information Uses Safety Supplier Related

1,4-Benzoquinone dioxime Basic information

Product Name:
1,4-Benzoquinone dioxime
Synonyms:
  • 1,4-Benzochinondioxim
  • 2,5-Cyclohexadiene-1,4-dione,dioxime
  • 1,4-CYCLOHEXADIENEDIONE DIOXIME
  • 1,4-QUINONE DIOXIME
  • 1,4-BENZOQUINONE DIOXIME
  • P-QUINONEDIOXIME=1,4-BENZOQUINONEDIOXIME
  • 1,4-BENZOQUINONE DIOXIME(P-BENZOQUINONE DIOXIME: P-QUINONE DIOXIME:PQD: QDO)
  • 4-BENZOQUINONEDIOXIME
CAS:
105-11-3
MF:
C6H6N2O2
MW:
138.12
EINECS:
203-271-5
Product Categories:
  • Nitrogen Compounds
  • Organic Building Blocks
  • Oximes
Mol File:
105-11-3.mol
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1,4-Benzoquinone dioxime Chemical Properties

Melting point:
243 °C (dec.)(lit.)
Boiling point:
253.51°C (rough estimate)
Density 
1,49 g/cm3
vapor pressure 
0Pa at 25℃
refractive index 
1.5100 (estimate)
Flash point:
°C
storage temp. 
Sealed in dry,Room Temperature
solubility 
dioxane: soluble0.1g/10 mL, clear
pka
9.12±0.20(Predicted)
form 
Solid
color 
White
Water Solubility 
<0.01 g/100 mL at 22.5 ºC
BRN 
2043234
Stability:
Stable. Incompatible with strong acids, strong oxidizing agents.
InChIKey
LNHURPJLTHSVMU-CGXWXWIYSA-N
LogP
0.3 at 35℃
CAS DataBase Reference
105-11-3(CAS DataBase Reference)
NIST Chemistry Reference
2,5-Cyclohexadiene-1,4-dione, dioxime(105-11-3)
IARC
3 (Vol. 29, Sup 7, 71) 1999
EPA Substance Registry System
p-Quinone dioxime (105-11-3)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
22-40
Safety Statements 
45-36/37-60
WGK Germany 
3
RTECS 
DK4900000
TSCA 
Yes
HS Code 
29280000
Hazardous Substances Data
105-11-3(Hazardous Substances Data)
Toxicity
LD50 oral in rat: 464mg/kg

MSDS

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1,4-Benzoquinone dioxime Usage And Synthesis

Uses

A rubber accelerator.

Chemical Properties

pale yellow to brown crystals or powder

Uses

p-Benzoquinone dioxime was used in oxidative regeneration of a variety of carbonyl compounds from their oximes using superoxide ion generated in situ by the phase transfer reaction between potassium superoxide and 18-crown-6.

Definition

ChEBI: Para-Benzoquinone dioxime is a quinone imine.

General Description

Pale yellow crystals or brown powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

1,4-Benzoquinone dioxime is incompatible with strong oxidizers and strong acids.

Fire Hazard

Flash point data for 1,4-Benzoquinone dioxime are not available; however, 1,4-Benzoquinone dioxime is probably combustible.

Flammability and Explosibility

Flammable

Biochem/physiol Actions

p-Benzoquinone dioxime is sex-specific rat carcinogen inducing tumours of the urinary bladder in female rats and is a direct-acting mutagen in Salmonella typhimurium TA982.

Safety Profile

Moderately toxic by ingestion. Questionable carcinogen with experimental neoplastigenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx,.

1,4-Benzoquinone dioxime Preparation Products And Raw materials

Raw materials

Preparation Products

1,4-Benzoquinone dioximeSupplier

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