BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE Chemical Properties

Melting point:

109-111 °C (lit.)

Boiling point:

380.7±42.0 °C(Predicted)

Density 

1.78±0.1 g/cm3(Predicted)

storage temp. 

2-8°C

solubility 

sol in a wide range of organic solvents.

color 

slightly yellow

BRN 

2141527

CAS DataBase Reference

38857-88-4

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

MSDS

• Language:English Provider:SigmaAldrich

BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE Usage And Synthesis

Chemical Properties

Yellow powder or crystals

Uses

Bis(2,2,2-trichloroethyl) azodicarboxylate has been used:

• in the asymmetric synthesis of substituted cycloalkyl[b]indoles
• as amination reagent during the aza-ene reaction of different alkenes to yield the corresponding allyl amines
• in para-directed amination of C₂-alkyl substituted anisole
• in the synthesis of acid- and base-sensitive azo compounds and in Diels-Alder cycloadditions

General Description

Thermal inverse-type hetero-Diels-Alder reaction of O-silyl-protected lactal and bis(2,2,2-trichloroethyl) azodicarboxylate has been reported.

storage

Bis(2,2,2-trichloroethyl) azodicarboxylate is same as with all azo compounds, caution should be exercised to avoid exposure of the material to heat. Store in a brown bottle.

BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE(38857-88-4)Related Product Information

• AZODICARBOXYLIC ACID DIMETHYL ESTER
• 1,1,1-Trichloroethane
• BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE
• Chloroform
• Diethyl azodicarboxylate
• Trichloroethanol
• AMMONIUM CARBAMATE
• 4-METHOXYBENZENESULFONAMIDE