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Tetrachloro-o-benzoquinone

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Tetrachloro-o-benzoquinone Basic information

Product Name:
Tetrachloro-o-benzoquinone
Synonyms:
  • 3,4,5,6-Tetrachlorocyclohexa-3,5-diene-1,2-dione
  • Tetrachloro-3,5-cyclohexadiene-1,2-dione
  • Tetrachloro-o-benzoquinone,97%
  • Tetrachloro-o-benzoquinone ,96%
  • 3,4,5,6-Tetrachlorocyclohexa-3,5-diene-1,2-dione, o-Chloranil
  • Tetrachloro-o-benzoquinone, 97% 25GR
  • Tetrachloro-o-benzoquinone, 97% 5GR
  • 3,4,5,6-Tetrachloro-1,2-benzoquinone 97%
CAS:
2435-53-2
MF:
C6Cl4O2
MW:
245.88
EINECS:
219-424-4
Product Categories:
  • Pesticide intermediate
  • Bi (Bismuth) Compounds
  • Synthetic Organic Chemistry
  • Classes of Metal Compounds
  • New Oxidation of primary & secondary Alcohols
  • Semimetal Compounds
  • Carbon Radical Producing Catalysts (Environmentally-friendly Oxidation)
  • Environmentally-friendly Oxidation
  • Oxidation
Mol File:
2435-53-2.mol
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Tetrachloro-o-benzoquinone Chemical Properties

Melting point:
126-129 °C(lit.)
Boiling point:
164.7±40.0 °C(Predicted)
Density 
1.7462 (estimate)
storage temp. 
2-8°C
solubility 
almost transparency in Methanol
form 
Fine Crystalline Powder
color 
Bordeaux
Water Solubility 
insoluble
BRN 
1309782
CAS DataBase Reference
2435-53-2(CAS DataBase Reference)
NIST Chemistry Reference
3,5-Cyclohexadiene-1,2-dione, 3,4,5,6-tetrachloro-(2435-53-2)
EPA Substance Registry System
o-Chloranil (2435-53-2)
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Safety Information

Hazard Codes 
Xi,N,Xn
Risk Statements 
36/37/38-50/53-36/38-20
Safety Statements 
26-36-61-60-37-22
RIDADR 
2811
WGK Germany 
3
HazardClass 
8
PackingGroup 
III
HS Code 
29147090

MSDS

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Tetrachloro-o-benzoquinone Usage And Synthesis

Chemical Properties

bordeaux fine crystalline powder

Uses

o-Chloranil is used as a reagent in the synthesis of fused triazolotriazines and triazolotriazepines which exhibit antibacterial activity. Also used as a reagent in the synthesis of nickel diimine catecholate charge-transfer complexes.

Synthesis Reference(s)

The Journal of Organic Chemistry, 46, p. 3056, 1981 DOI: 10.1021/jo00328a013

Purification Methods

Crystallise o-chloranil from AcOH. Dry it in vacuum desiccator over KOH. [Beilstein 7 IV 2068.]

Tetrachloro-o-benzoquinone Preparation Products And Raw materials

Raw materials

Tetrachloro-o-benzoquinoneSupplier

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