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CIS-1,4-HEXADIENE

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CIS-1,4-HEXADIENE Basic information

Product Name:
CIS-1,4-HEXADIENE
Synonyms:
  • CIS-1,4-HEXADIENE
  • (4Z)-1,4-Hexadiene
  • (z)-1,4-hexadiene
  • 1,4-Hexadiene, (Z)-
  • Nsc157585
  • cis-1,4-Hexadiene >=99.0%
  • (z)-4-hexadiene
  • (Z)-CH2=CHCH2CH=CHCH3
CAS:
7318-67-4
MF:
C6H10
MW:
82.14
EINECS:
230-783-6
Product Categories:
  • Acyclic
  • Alkenes
  • Organic Building Blocks
Mol File:
7318-67-4.mol
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CIS-1,4-HEXADIENE Chemical Properties

Melting point:
-94.9°C (estimate)
Boiling point:
65-66 °C (lit.)
Density 
0.707 g/mL at 20 °C (lit.)
refractive index 
n20/D 1.415
Flash point:
-46 °C
BRN 
1839519
LogP
2.910 (est)
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Safety Information

Hazard Codes 
F,Xn
Risk Statements 
11-65
Safety Statements 
16-62
RIDADR 
UN 2458 3/PG 2
WGK Germany 
3
RTECS 
MM1997000

MSDS

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CIS-1,4-HEXADIENE Usage And Synthesis

General Description

cis-1,4-Hexadiene can be synthesized from the cobalt-catalyzed reaction between butadiene and ethylene. The reaction of this hydrocarbon with Fe(CO)5 affords the trans-1,3-hexadiene-iron tricarbonyl complex (I), plus a small amount of the trans,trans-2,4-hexadiene complex(II). Mechanism of the conversion of cis-1,4-hexadiene to trans-2-methyl-1,3-pentadiene, via rearrangement in the presence of a nickel catalyst has been investigated.

CIS-1,4-HEXADIENESupplier

Energy Chemical
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Shanghai Hanhong Scientific Co.,Ltd.
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Shandong Xiya Chemical Co., Ltd
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Sigma-Aldrich
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BOC Sciences
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