BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE Chemical Properties

Melting point:

100-104 °C(lit.)

Boiling point:

291℃

Flash point:

130℃

storage temp. 

Store under inert gas

pka

4.50±0.70(Predicted)

form 

Powder

color 

white to off-white

Sensitive 

air sensitive, moisture sensitive

CAS DataBase Reference

56183-63-2(CAS DataBase Reference)

Safety Information

Hazard Codes 

C

Risk Statements 

14-34

Safety Statements 

26-27-28-36/37/39-45

RIDADR 

UN 3261 8/PG 1

WGK Germany 

3

HazardClass 

8

PackingGroup 

II

HS Code 

29310099

MSDS

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BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE Usage And Synthesis

Description

Bis(diisopropylamino)chlorophosphine is a white to off-white powder to crystalline organophosphorus compound, mainly used as an organic synthetic raw material or reaction reagent. It can be used in the synthesis of mixed phosphorothioate and methylenephosphine derivatives, etc. It is commonly used in chemical production and laboratory research.

Chemical Properties

white to light yellow crystal powde

Uses

Bis(diisopropylamino)chlorophosphine has been used in the synthesis of tert-butyl tetraisopropylphosphorodiamidite ligand for palladium-catalyzed Buchwald–Hartwig amination reaction.

It is also can be used to synthesize:

• acyclic N-phosphonio imine catalyst for selective epoxidations
• boryl-substituted methylenephosphonium derivatives

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE(56183-63-2)Related Product Information

• Isopropylamine
• BIS(DIETHYLAMINO)CHLOROPHOSPHINE
• BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE
• BIS(DIMETHYLAMINO)CHLOROPHOSPHINE
• BIS(DIISOPROPYLAMINO)-PHOSPHINE