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Di-tert-butylchlorophosphane

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Di-tert-butylchlorophosphane Basic information

Product Name:
Di-tert-butylchlorophosphane
Synonyms:
  • AURORA KA-1319
  • Bis(1,1-dimethylethyl)-phosphinous chloride
  • DI-T-BUTYLCHLOROPHOSPHINE
  • DI-T-BUTYLPHOSPHINOUS CHLORIDE
  • DI-TERT-BUTYLPHOSPHORUS CHLORIDE
  • DI-TERT-BUTYLCHLOROPHOSPHANE
  • DI-TERT-BUTYLCHLOROPHOSPHINE
  • DI-TERT-BUTYLCHLOROPHO
CAS:
13716-10-4
MF:
C8H18ClP
MW:
180.66
EINECS:
237-266-4
Product Categories:
  • organophosphine halide
  • Catalysis and Inorganic Chemistry
  • Ligand
  • Phosphorus Compounds
  • Phosphorus Precursors
  • Phosphines
  • Chlorophosphines
  • Achiral Phosphine
  • Alkyl Phosphine
  • P-Cl
Mol File:
13716-10-4.mol
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Di-tert-butylchlorophosphane Chemical Properties

Melting point:
2-3°C
Boiling point:
48 °C/3 mmHg (lit.)
Density 
0.951 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.482(lit.)
Flash point:
142 °F
solubility 
Miscible with terahydrofuran.
form 
Liquid
Specific Gravity
0.951
color 
Clear colorless
Sensitive 
Air & Moisture Sensitive
InChIKey
MCRSZLVSRGTMIH-UHFFFAOYSA-N
CAS DataBase Reference
13716-10-4(CAS DataBase Reference)
NIST Chemistry Reference
Phosphinous chloride, bis(1,1-dimethylethyl)-(13716-10-4)
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Safety Information

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45-25
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
TSCA 
No
HazardClass 
8
PackingGroup 
II
HS Code 
29310099

MSDS

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Di-tert-butylchlorophosphane Usage And Synthesis

Chemical Properties

Colorless to light yellow liqui

Uses

Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

Uses

Di-tert-butylchlorophosphine is used as a catalyst in organic synthesis.

Uses

Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.

Application

Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.

Precautions

Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.

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