Di-tert-butylchlorophosphane Chemical Properties

Melting point:

2-3°C

Boiling point:

48 °C/3 mmHg (lit.)

Density 

0.951 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.482(lit.)

Flash point:

142 °F

solubility 

Miscible with terahydrofuran.

form 

Liquid

Specific Gravity

0.951

color 

Clear colorless

Sensitive 

Air & Moisture Sensitive

InChIKey

MCRSZLVSRGTMIH-UHFFFAOYSA-N

CAS DataBase Reference

13716-10-4(CAS DataBase Reference)

NIST Chemistry Reference

Phosphinous chloride, bis(1,1-dimethylethyl)-(13716-10-4)

Safety Information

Hazard Codes 

C

Risk Statements 

34

Safety Statements 

26-36/37/39-45-25

RIDADR 

UN 3265 8/PG 2

WGK Germany 

3

TSCA 

No

HazardClass 

8

PackingGroup 

II

HS Code 

29310099

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich

Di-tert-butylchlorophosphane Usage And Synthesis

Chemical Properties

Colorless to light yellow liqui

Uses

Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

Uses

Di-tert-butylchlorophosphine is used as a catalyst in organic synthesis.

Uses

Bulky ligand used with Pd(OAc)₂ in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.

Application

Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.

Precautions

Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.

Di-tert-butylchlorophosphane(13716-10-4)Related Product Information

• DI-T-BUTYLPHOSPHINE OXIDE
• 2-Di-t-butylphosphino-4-Methoxy-3,5,6-triMethyl-2',4',6'-tri-i-propylbiphenyl, Min. 98% [~1:1 Mixture with regioisoMer, 2-Di-t-butylphosphino-5-Methoxy-3,4,6-triMethyl-2',4',6'-tri-i-propylbiphenyl]
• Lithium Aluminum Hydride
• Tetrakis(hydroxymethyl)phosphonium sulfate
• T-BUTYLPHOSPHINE
• DIBROMO(CHLORODI-TERT-BUTYLPHOSPHINE)PALLADIUM (II) DIMER
• DICHLOROBIS(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II)
• DI-1-ADAMANTYLPHOSPHINIC CHLORIDE
• DI-TERT-BUTYLCHLOROPHOSPHINE BORANE COMPLEX
• Di-tert-butylchlorophosphane
• DIBROMO(CHLORODI-T-BUTYLPHOSPHINE)PALLADIUM(II) DIMER
• AURORA KA-1706
• DICHLORO(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II) DIMER
• AURORA KA-1182