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ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometallic compounds >  Organic palladium >  1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER

1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER

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1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER Basic information

Product Name:
1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER
Synonyms:
  • BIS[1,3-DIHYDRO-1,3-(2,4,6-TRIMETHYLPHENYL)-2H-IMIDAZOL-2-YLIDENE]BIS[MU-[(2,3-ETA)-1,4-NAPHTHALENEDIONE-KAPPAO]]DI-PALLADIUM
  • PD(0)-NAPHTHOCHINONE-1,3-BIS(2,4,6-TRI-METHYLPHENYL)IMIDAZOL-2-YLIDENE
  • NAPHTHOQUINONE-1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLE-2-YLIDENEPALLADIUM(0)
  • 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene(1,4-naphthoquinone)palladium(0)dimer,96%
  • bis[1,3-dihydro-1,3-(2,4,6-trimethylphenyl)-2h-imidazol-2-ylidene]bis[μ-[(2,3-η)-1,4-naphthalenedione-κo]]di-palladium
  • NAPHTHOQUINONE-1,3-BIS(MESITYL)IMIDAZOLE-2-YLIDENEPALLADIUM(0)
  • 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium dimer
  • Umicore CX12
CAS:
467220-49-1
MF:
2C21H24N2Pd.2C10H6O2
MW:
1138.02
Product Categories:
  • Pd
  • organometallic complex
Mol File:
467220-49-1.mol
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1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER Chemical Properties

Melting point:
>300 °C
form 
Powder
color 
orange-red
Sensitive 
air sensitive
CAS DataBase Reference
467220-49-1
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38-43
Safety Statements 
26-36/37
WGK Germany 
3
HS Code 
28439000

MSDS

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1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER Usage And Synthesis

Reaction

  1. Catalyst for Heck reactions in ionic liquids.
  2. Catalyst for the cross-coupling of aryl diazonium salts.
  3. Catalyst for the Kumada cross-coupling of alkyl chlorides.

Chemical Properties

Orange crystal

Uses

It can be used as a catalyst in the Kumada cross-coupling of aryl magnesium reagents with functionalized alkyl chlorides at room temperature to form substituted alkanes.

General Description

1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer is an N-heterocyclic carbene based palladium catalyst that shows high catalytic activity in C-C coupling reactions.

1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMERSupplier

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