Perfluoro(2-methyl-3-pentanone) Chemical Properties

Melting point:

-108°C

Boiling point:

49°C

Density 

1,6 g/cm³

vapor pressure 

31.6-40.4kPa at 20-25℃

solubility 

Chloroform (Soluble), Methanol (Sparingly)

form 

clear liquid

Specific Gravity

1.6

color 

Colorless to Almost colorless

Water Solubility 

24-332.6mg/L at 25℃

InChI

InChI=1S/C6F12O/c7-2(4(10,11)12,5(13,14)15)1(19)3(8,9)6(16,17)18

InChIKey

RMLFHPWPTXWZNJ-UHFFFAOYSA-N

SMILES

C(F)(F)(F)C(F)(F)C(=O)C(F)(C(F)(F)F)C(F)(F)F

LogP

2.79-5.48 at 20-25℃

EPA Substance Registry System

3-Pentanone, 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)- (756-13-8)

Safety Information

Hazard Codes 

Xi

TSCA 

T

HazardClass 

IRRITANT

HS Code 

2914790040

Perfluoro(2-methyl-3-pentanone) Usage And Synthesis

Chemical Properties

Colorless to almost transparent liquid

Uses

Perfluoro(2-methyl-3-pentanone) has outstanding flame retardant effect to prevent burning and is used in the protection of molten magnesium and fire extinguishing agents with no impact on the environment.

Preparation

158 g of perfluoro-2,3-epoxy-2-methyl pentane, 2.9 g of potassium fluoride, 6 g of sulfolane and 100 mL of diglyme are added into a 500 mL three-neck flask equipped with a reflux condensing tube and a mechanical stirring device, respectively. The temperature is raised to be 30 °C after stir starts. After 3 hours of reaction, the reaction product of Perfluoro(2-methyl-3-pentanone) is analyzed by gas chromatography.

Flammability and Explosibility

Not classified

Industrial uses

Perfluoro(2-methyl-3-pentanone) can be used as a wet cleaning agent to clean steam reactors and their components, as well as to clean unwanted deposits accumulated in gas phase reactors and etch dielectric or metallic materials in gas phase reactors.

Environmental considerations

Perfluoro(2-methyl-3-pentanone) is a commonly used fire-fighting fluid. The photolysis of Perfluoro(2-methyl-3-pentanone) gives CF3CF2C·(O) and ·CF(CF3)2 radicals. This compound can undergo hydrolysis to produce PFPrA and CF3CFHCF3 (HFC-227ea) in a manner analogous to the Haloform reaction. The atmospheric fate of Perfluoro(2-methyl-3-pentanone) seems to be direct photolysis, which, under low NOx conditions, gives PFPrA a small yield[1].
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS) classifies this chemical as H412 - Harmful to aquatic life with long-lasting effects. Photolysis in sunlight, hydrolysis, and hydration may be a significant sink of Perfluoro(2-methyl-3-pentanone) in the environment.

References

[1] Jackson, Derek A. , et al. "Atmospheric Degradation of Perfluoro-2-methyl-3-pentanone: Photolysis, Hydrolysis and Hydration." Environmental Science & Technology 45.19(2011):p.8030-8036.

Perfluoro(2-methyl-3-pentanone) (756-13-8)Related Product Information

• Fipronil
• Bromotrichloromethane
• (Perfluorobutyl)ethylene
• 1,1,1,3,3,3-Hexafluoro-2-propanol
• Sulfluramid
• difluoroethane
• Hexafluoropropylene
• Difluorochloromethane
• Afloqualone
• Trifluoroacetyl chloride
• Sulfuryl chloride
• Poly(propylene glycol) bis(2-aminopropyl ether)
• 1,1,1,2,3,3,3-Heptafluoropropane
• 1,3-DIFLUOROACETONE
• Perfluoro(2-methyl-3-pentanone)
• 2-METHYL-3-PENTANONE
• PENTAFLUOROETHYL ETHYL KETONE