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2-Amino-4-chlorophenol-6-sulfonic acid

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2-Amino-4-chlorophenol-6-sulfonic acid Basic information

Product Name:
2-Amino-4-chlorophenol-6-sulfonic acid
Synonyms:
  • 3-amino-5-chloro-2-hydroxy-benzenesulfonicaci
  • Metanilic acid, 5-chloro-2-hydroxy-
  • Metanilic acid, 5-chloro-2-hydroxy- (8CI)
  • 6-AMINO-4-CHLORO-1-PHENOL-2-SULPHONICACID
  • 2-Amino-4-chlorphenol-6-sulfonsure
  • 6-Amino-4-chlorophenol-2-sulfonic acid
  • BENZENESULFONICACID,3-AMINO-5-CHLORO-2-HYDROXY
  • 2-Amino-4-chlorophenyl-6-sulfonic acid
CAS:
88-23-3
MF:
C6H6ClNO4S
MW:
223.63
EINECS:
201-813-5
Product Categories:
  • Intermediates of Dyes and Pigments
Mol File:
88-23-3.mol
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2-Amino-4-chlorophenol-6-sulfonic acid Chemical Properties

Density 
1.790±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
powder to crystal
pka
-1.53±0.50(Predicted)
color 
White to Almost white
CAS DataBase Reference
88-23-3(CAS DataBase Reference)
EPA Substance Registry System
2-Hydroxy-5-chlorometanilic acid (88-23-3)
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Safety Information

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
22-24/25-26-39
RIDADR 
2811
HS Code 
2922.29.8190
HazardClass 
6.1
PackingGroup 
III

MSDS

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2-Amino-4-chlorophenol-6-sulfonic acid Usage And Synthesis

Uses

The acid is an important intermediate for dyes. It is used mainly in the manufacture of Diamond Black P 2 B and of acid chrome blue dyes.

Production Methods

2-Amino-4-chlorophenol-6-sulfonic acid obtained from p-chlorophenol by sulfonation and nitration is reduced with iron and hydrochloric acid without being precipitated. After filtering from the iron sludge, the highly alkaline reduction liquor is concentrated by evaporation and decolorized with activated carbon. Upon acidification 3-amino-5-chloro-2-hydroxybenzenesulfonic acid precipitates. Yield 72 %, based on p-chlorophenol.

General Description

Off-white solid.

Air & Water Reactions

May be sensitive to prolonged exposure to air and/or light. Insoluble in water.

Reactivity Profile

2-Amino-4-chlorophenol-6-sulfonic acid may react with strong oxidizing or reducing agents and with mineral acids and bases

Fire Hazard

Flash point data are not available for 2-Amino-4-chlorophenol-6-sulfonic acid, but 2-Amino-4-chlorophenol-6-sulfonic acid is probably combustible.

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