Basic information Safety Supplier Related

(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE

Basic information Safety Supplier Related

(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE Basic information

Product Name:
(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE
Synonyms:
  • (2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE
  • (2R,3R)-(-)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene,min.95%(R,R)-NORPHOS
  • (2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE (R,R)-NORPHOS
  • (R,R)-NORPHOS
  • (-)-NORPHOS
  • (2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO) B IC.(2.2.1)HEPT-5-EN
  • (2R,3R)-(-)-2,3-Bis(diphenylphosphino)-bicylo[2.2.1]hept-5-ene
  • (1α,4α)-5β,6α-Bis(diphenylphosphino)bicyclo[2.2.1]hepta-2-ene
CAS:
71042-55-2
MF:
C31H28P2
MW:
462.51
Product Categories:
  • Chiral Phosphine
  • NORPhos Series
  • organophosphine ligand
Mol File:
71042-55-2.mol
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(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE Chemical Properties

Melting point:
120-125 °C
alpha 
-47° (c 1, CHCl3)
Boiling point:
577.0±50.0 °C(Predicted)
storage temp. 
2-8°C
form 
crystal
color 
white
Sensitive 
air sensitive
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
10-23
TSCA 
No
HS Code 
2931.90.6000

MSDS

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(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE Usage And Synthesis

Reactions

  1. Ligand used in the enantioselective rhodium catalyzed hydrogenation of α–dehydroaminoesters and enamides.
  2. Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
  3. Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.
  4. Iridium or Rhodium-catalyzed asymmetric Diels-Alder reaction.

(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENESupplier

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