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3,3',4,4'-TETRACHLOROBIPHENYL

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3,3',4,4'-TETRACHLOROBIPHENYL Basic information

Product Name:
3,3',4,4'-TETRACHLOROBIPHENYL
Synonyms:
  • PCB NO 77
  • PCB-77
  • BZ NO 77
  • BALLSCHMITER NO 77
  • 3,3',4,4'-TETRACHLOROBIPHENYL
  • 3,3',4,4'-PCB
  • 3,3',4,4'-Tetrachloro-1,1'-biphenyl
  • 3,3’,4,4’-tetrachloro-1,1’-biphenyl
CAS:
32598-13-3
MF:
C12H6Cl4
MW:
291.99
Mol File:
32598-13-3.mol
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3,3',4,4'-TETRACHLOROBIPHENYL Chemical Properties

Melting point:
182-184℃
Boiling point:
374.95°C (rough estimate)
Density 
1.4420 (rough estimate)
refractive index 
1.6120 (rough estimate)
Flash point:
100 °C
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Dichloromethane (Slightly)
color 
Pale Grey
Water Solubility 
0.5489ug/L(25 ºC)
BRN 
2051251
InChIKey
UQMGJOKDKOLIDP-UHFFFAOYSA-N
EPA Substance Registry System
3,3',4,4'-Tetrachlorobiphenyl (32598-13-3)
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Safety Information

Hazard Codes 
N
Risk Statements 
33-50/53
Safety Statements 
35-60-61
RIDADR 
2315
WGK Germany 
3
RTECS 
DV8650000
HazardClass 
9
PackingGroup 
II
Hazardous Substances Data
32598-13-3(Hazardous Substances Data)
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3,3',4,4'-TETRACHLOROBIPHENYL Usage And Synthesis

Uses

3,3'',4,4''-Tetrachlorobiphenyl is a polychlorinated biphenyl (PCB) congeners.

Definition

ChEBI: A tetrachlorobiphenyl that is biphenyl in which the hydrogens at position 3 and 4 on each phenyl group are replaced by chlorines.

Safety Profile

Poison by ingestion. An experimental teratogen. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl-. See also POLYCHLORINATED BIPHENYLS.

Metabolic pathway

When 3,4,3',4' -tetrachlorobiphenyl (TCB) is orally administered to rats, seven hydroxylated metabolites are identified in the rat feces. The major metabolites are 5-hydroxy-3,4,3',4' -TCB and 4-hydroxy-3,5,3',4' - TCB. One further metabolite isolated is an oxepin, existing in a state of equilibration with the 4',5' - epoxide of the major metabolite, 4-hydroxy-3,5,3',4' -TCB.

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