Basic information Safety Supplier Related

RuPhos Pd G2

Basic information Safety Supplier Related

RuPhos Pd G2 Basic information

Product Name:
RuPhos Pd G2
Synonyms:
  • Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [RuPhos Palladacycle]
  • RuPhos Pd G2
  • Chloro(2-dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
  • Chloro(2-dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • 2nd Generation RuPhos Precatalyst
  • (2'-Amino-[1,1'-biphenyl]-2-yl)(dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphoranyl)palladium(III) chloride
  • Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2-amino-1,1'-biphenyl-2-yl)palladium(II)
  • [2'-(Amino)[1,1'-biphenyl]-2-yl][[2',6'-bis(1-methylethoxy)[1,1'-biphenyl]-2-yl]dicyclohexylphosphine]chloropalladium
CAS:
1375325-68-0
MF:
C42H53ClNO2PPd
MW:
776.73
Product Categories:
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Others
  • Pd
Mol File:
1375325-68-0.mol
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RuPhos Pd G2 Chemical Properties

Melting point:
195-197°C
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
Powder
color 
white
InChI
InChI=1S/C30H43O2P.C12H9N.ClH.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-6,8-9,13H;1H;/q;-2;;+2
InChIKey
HAGBKELACJTOCE-UHFFFAOYSA-N
SMILES
P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1OC(C)C)OC(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-]
CAS DataBase Reference
1375325-68-0
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Safety Information

WGK Germany 
3
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RuPhos Pd G2 Usage And Synthesis

Uses

RuPhos Pd G2 may be employed as precatalyst in the preparation of fluoro-substituted diazatetracenes and diazapentacenes, via Pd-catalyzed aryl amination reaction.

Reactions

Palladium precatalyst for fast Suzuki-Miyaura coupling reactions.

General Description

RuPhos Pd G2 is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N, and C-O bond formation reactions and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases.

reaction suitability

reagent type: catalyst

RuPhos Pd G2Supplier

WuHan Taiyukaishang Chemical Co., Ltd. Gold
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027-027-87680032 18963957250
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taiyuchem@163.com
Beijing Guofang Dingsheng Technology Co., Ltd. Gold
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18610472091 18610472091
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gfdskj@163.com
Wu Han Lbpchem Chemical Co., Ltd. Gold
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02763499399 13797220777
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lpbchem@163.com
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. Gold
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0371-65511006 18625597674
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sales@kingorgchem.com
Leshan Bangsheng New Materials Co., Ltd Gold
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0833-2599138 19162614312
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lsbangsheng@126.com