RuPhos Pd G2 Chemical Properties

Melting point:

195-197°C

storage temp. 

under inert gas (nitrogen or Argon) at 2–8 °C

form 

Powder

color 

white

InChI

InChI=1S/C30H43O2P.C12H9N.ClH.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-6,8-9,13H;1H;/q;-2;;+2

InChIKey

HAGBKELACJTOCE-UHFFFAOYSA-N

SMILES

P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1OC(C)C)OC(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-]

CAS DataBase Reference

1375325-68-0

Safety Information

WGK Germany 

3

RuPhos Pd G2 Usage And Synthesis

Uses

RuPhos Pd G2 may be employed as precatalyst in the preparation of fluoro-substituted diazatetracenes and diazapentacenes, via Pd-catalyzed aryl amination reaction.

Reactions

Palladium precatalyst for fast Suzuki-Miyaura coupling reactions.

General Description

RuPhos Pd G2 is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N, and C-O bond formation reactions and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases.

RuPhos Pd G2(1375325-68-0)Related Product Information

• XPhos Pd G1
• RuPhos Pd G3
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• RuPhos Pd G1 Methyl t--Butyl Ether Adduct
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• SPhos Pd G3