Basic information Safety Supplier Related

2-NITROTOLUENE-4-SULFONIC ACID

Basic information Safety Supplier Related

2-NITROTOLUENE-4-SULFONIC ACID Basic information

Product Name:
2-NITROTOLUENE-4-SULFONIC ACID
Synonyms:
  • 1-METHYL-2-NITROBENZENE-4-SULFONIC ACID
  • 2-NITROTOLUENE-4-SULFONIC ACID
  • 4-METHYL-3-NITROBENZENSULFONIC ACID
  • 4-METHYL-3-NITROBENZENE SULFONIC ACID
  • 4-methyl-3-nitro-benzenesulfonicaci
  • ortho-nitro-toluene-para-sulphonicacid
  • 2-nitro-p-toluenesulphonic acid
  • 2-Nitro-4-Toluene Sulfonic Acid
CAS:
97-06-3
MF:
C7H7NO5S
MW:
217.2
EINECS:
202-556-1
Product Categories:
  • Intermediates of Dyes and Pigments
Mol File:
97-06-3.mol
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2-NITROTOLUENE-4-SULFONIC ACID Chemical Properties

Melting point:
92°C
Boiling point:
500°C (rough estimate)
Density 
1.6040 (rough estimate)
refractive index 
1.6100 (estimate)
pka
-1.04±0.50(Predicted)
EPA Substance Registry System
Benzenesulfonic acid, 4-methyl-3-nitro- (97-06-3)
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2-NITROTOLUENE-4-SULFONIC ACID Usage And Synthesis

Physical properties

2-Nitrotoluene-4-sulfonic Acid, crystallizes from water as pale yellow hygroscopic needles of the dihydrate.

Uses

The total liquor of 2-Nitrotoluene-4-sulfonic Acid is hydrogenated in situ to give o-toluidine-4-sulfonic acid [618-03-1]. Isolated 2-nitrotoluene-4- sulfonic acid may be converted to 2-nitro-p-toluenesulfonyl chloride [54090-41-4], but the preferred process for [54090-41-4] is chlorosulfonation of 2-nitrotoluene. Reaction of [54090-41-4] with dimethylamine followed by reduction gives 3-amino-4-methyl-N,N-dimethylbenzenesulfonamide [6331-68-6] for use as an azoic diazo component.

Production Methods

2-Nitrotoluene is sulfonated by heating with 25 % oleum at 80 ℃ for 3 h, then quenching and liming to give a neutral solution of the sodium salt of 2-Nitrotoluene-4-sulfonic Acid.

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