AdBrettPhos Pd G3
AdBrettPhos Pd G3 Basic information
- Product Name:
- AdBrettPhos Pd G3
- Synonyms:
-
- Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), AdBrettPhos Palladacycle Gen. 3
- METHANESULFONATO[2-(DI-1-ADAMANTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ADBRETTPHOSPALLADACYCLEGEN.3]
- Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- AdBrettPhos Palladacycle Gen. 3
- bis(adamantan-1-yl)[3,6-dimethoxy-2',4',6'-tris(pro pan-2-yl)-[1,1'-biphenyl]-2-yl]phosphane
- Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2...
- AdBrettPhos Pd G3
- bis(1-adamantyl)-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane
- CAS:
- 1445972-29-1
- MF:
- C56H74NO5PPdS
- MW:
- 1010.66
- Mol File:
- 1445972-29-1.mol
AdBrettPhos Pd G3 Chemical Properties
- Melting point:
- 251-253 °C
- storage temp.
- 2-8°C, protect from light, stored under nitrogen
- form
- solid
- color
- brown to green
- InChIKey
- OZFYYHNERORONM-UHFFFAOYSA-M
AdBrettPhos Pd G3 Usage And Synthesis
Reaction
Palladium catalyst used in the highly selective monoarylation of ammonia.
Uses
Buchwald 3rd Generation Pd Precatalyst adorned by the bulk di-adamntyl BrettPhos ligand. This complex has been used in the monoarylation of ammonia, displaying apptitude for otherwise difficult 5-member heterocyclic substrates.
Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
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