ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic rhodium > Chlorobis(cyclooctene)rhodium(I) dimer
Chlorobis(cyclooctene)rhodium(I) dimer
Chlorobis(cyclooctene)rhodium(I) dimer Basic information
- Product Name:
- Chlorobis(cyclooctene)rhodium(I) dimer
- Synonyms:
-
- [RhCl(cis-cyclooctene)2]2
- CHLOROBIS(CYCLOOCTENE)RHODIUM(I) DIMER
- Chlorobis(cyclooctene)rhodium(I)
- Chlorobis(cyclooctene)rhodium(I)dimere
- Chlorobis(cyclooctene)rhodium(I)dimer,min.98%
- Chlorobis(cyclooctene)rhodium(I) dimer, min. 98%
- Chlorobis(cyclooctene)rhodium(I) dimer,98%
- CHLOROBIS(CYCLOOCTENE)RHODIUM()DIMER
- CAS:
- 12279-09-3
- MF:
- C32H56Cl2Rh2
- MW:
- 717.5
- EINECS:
- 623-340-7
- Product Categories:
-
- Rh
- organometallic complex
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Homogeneous Catalysts
- Metal Complexes
- Rh (Rhodium) Compounds
- Synthetic Organic Chemistry
- Transition Metal Compounds
- Catalysis and Inorganic Chemistry
- Chemical Synthesis
- Rhodium
- Mol File:
- 12279-09-3.mol
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Chlorobis(cyclooctene)rhodium(I) dimer Chemical Properties
- Melting point:
- 190 °C (dec.) (lit.)
- storage temp.
- Freezer
- form
- crystal
- color
- orange to red
- Sensitive
- air sensitive, store cold
- CAS DataBase Reference
- 12279-09-3
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Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-37/39
- WGK Germany
- 3
- TSCA
- No
- HS Code
- 28439000
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
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Chlorobis(cyclooctene)rhodium(I) dimer Usage And Synthesis
Chemical Properties
orange-brown powder
Uses
Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst:
- To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.
- In direct C-arylation of N-unprotected indoles and pyrroles.
- In the carboxylation of arenes via C-H bond activation.
Uses
Chlorobis(cyclooctene)rhodium(I) dimer is an organometallic complex used as a catalyst in the arylzincation of alkynes. It is also used as a building block for other Rh-based catalysts, such as the preparation of rhodium bis(phosphinimine)pyrrole pincer carbonyl complexes for deoxygenative metathesis of CO.
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Chlorobis(cyclooctene)rhodium(I) dimer(12279-09-3)Related Product Information
- DILINOLEIC ACID
- Chlorobis(ethylene)rhodium (I) dimer
- POLYALUMINUM CHLORIDE
- Rhodium(III) Chloride
- Rhodium
- methoxy(cyclooctadiene)rhodium(i) dimer
- Acetylacetonatobis(ethylene)rhodium(I)
- BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE
- POLYETHYLENE, CHLORINATED
- Chlorinated polyethylene water-proof rolled materials
- cis-Cyclooctene
- ALKYLKETENE DIMER
- CYCLOOCTENE
- Chlorobis(cyclooctene)rhodium(I) dimer