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2-Amino-3-chlorobenzoic acid

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2-Amino-3-chlorobenzoic acid Basic information

Product Name:
2-Amino-3-chlorobenzoic acid
Synonyms:
  • 2-AMINO-3-CHLOROBENZOIC ACID
  • BUTTPARK 24\07-98
  • 3-CHLORO-2-AMINOBENZOIC ACID
  • 3-CHLOROANTHRANILIC ACID
  • TIMTEC-BB SBB003844
  • 2-Amino-3-chloro
  • 2-Amino-3-chlorbenzoesure
  • 3-Chloroanthranilic acid (COOH=1)
CAS:
6388-47-2
MF:
C7H6ClNO2
MW:
171.58
EINECS:
228-996-4
Product Categories:
  • Amines
  • Aromatics
  • FINE Chemical & INTERMEDIATES
  • Phenylacetic acid
  • Organic acids
  • Miscellaneous Reagents
  • benzene derivative
  • Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
  • bc0001
Mol File:
6388-47-2.mol
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2-Amino-3-chlorobenzoic acid Chemical Properties

Melting point:
189-191 °C (lit.)
Boiling point:
0°C
Density 
1.476±0.06 g/cm3(Predicted)
Flash point:
0°C
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
DMSO, Methanaol
pka
4.57±0.10(Predicted)
form 
Solid
color 
Yellow to brown
Water Solubility 
Soluble in water.
Sensitive 
Air & Light Sensitive
InChI
InChI=1S/C7H6ClNO2/c8-5-3-1-2-4(6(5)9)7(10)11/h1-3H,9H2,(H,10,11)
InChIKey
LWUAMROXVQLJKA-UHFFFAOYSA-N
SMILES
C(O)(=O)C1=CC=CC(Cl)=C1N
CAS DataBase Reference
6388-47-2(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39-36
WGK Germany 
1
Hazard Note 
Irritant
HS Code 
29224999

MSDS

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2-Amino-3-chlorobenzoic acid Usage And Synthesis

Chemical Properties

white to yellow, tan or grey crystalline powder

Uses

2-Amino-3-chlorobenzoic acid is used as pharmaceutical intermediates.

Uses

2-Amino-3-chlorobenzoic Acid is a plant growth regulator.    

Synthesis Reference(s)

The Journal of Organic Chemistry, 17, p. 141, 1952 DOI: 10.1021/jo01135a014

Synthesis

The synthesis of 2-Amino-3-chlorobenzoic acid is as follows:
70 ml of methanol was added to an autoclave, and cooled to -70° C., and 16 g (942 mmol) of a generated ammonia gas was added. 30 g (157 mmol) of 2,3-dichlorobenzoic acid and 0.78 g (7.85 mmol) of copper(I) chloride were added. The autoclave was sealed, and heated in an oil bath at 130° C. and 30 atmospheres for 20 hours. After the completion of the reaction, the autoclave was cooled to room temperature, and the reaction mixture was transferred into a reaction flask. 100 ml of water was added to the reaction solution, and the reaction solution was heated in an oil bath to 100° C. to remove the ammonia and the methanol. Then, the reaction solution was cooled to room temperature, and hydrochloric acid was added to adjust the pH value to 3. The precipitated crystals were filtered and dried to obtain 21.8 g of 2-amino-3-chlorobenzoic acid as white crystals with a yield of 81%.

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