ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic rhodium > (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Basic information
- Product Name:
- (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- Synonyms:
-
- (+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%
- (-)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (S,S)-Me-BPE-Rh
- (à)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetat
- (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(S,S)-Me-BPE-Rh
- (S,S)-ME-BPE-RH
- (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh
- (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE,98+%(S,S)-ME-BPE-RH
- CAS:
- 213343-65-8
- MF:
- C22H40BF4P2Rh-
- MW:
- 556.21
- Product Categories:
-
- Chiral Catalysts, Ligands, and Reagents
- DuPhos/BPE
- Privileged Ligands and Complexes
- organometallic complex
- Mol File:
- 213343-65-8.mol
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(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Chemical Properties
- Melting point:
- 152.2-156.3 °C
- form
- Crystalline Powder
- color
- Orange to red to brown
- Sensitive
- air sensitive
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Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 22-24/25-26
- WGK Germany
- 3
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(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Usage And Synthesis
Reaction
The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
Uses
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
Catalyst for:
- Asymmetric hydrogenation
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATESupplier
J & K SCIENTIFIC LTD.
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- 010-82848833 400-666-7788
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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- 4006608290; 18621169109
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Alfa Aesar
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BeiJing Hwrk Chemicals Limted
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Energy Chemical
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- 021-021-58432009 400-005-6266
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(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE(213343-65-8)Related Product Information
- 1,3-CYCLOOCTADIENE
- (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
- 1,2-BIS(DIETHYLPHOSPHINO)ETHANE