ALLYLTRIMETHYLGERMANE
ALLYLTRIMETHYLGERMANE Basic information
- Product Name:
- ALLYLTRIMETHYLGERMANE
- Synonyms:
-
- ALLYLTRIMETHYLGERMANE
- (2-Propenyl)trimethylgermane
- trimethyl(prop-2-enyl)germane
- Germane, trimethyl-2-propen-1-yl-
- CAS:
- 762-66-3
- MF:
- C6H14Ge
- MW:
- 158.82
- Mol File:
- 762-66-3.mol
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ALLYLTRIMETHYLGERMANE Chemical Properties
- Boiling point:
- 101°C
- Density
- 0,995 g/cm3
- refractive index
- 1.4333
- Flash point:
- 16°C
- solubility
- sol ether, hexane, and dichloromethane; insol H2O
- Specific Gravity
- 0.995
- Hydrolytic Sensitivity
- 1: no significant reaction with aqueous systems
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ALLYLTRIMETHYLGERMANE Usage And Synthesis
Uses
ALLYLTRIMETHYLGERMANE is an allylation reagent for electrophilic and nucleophilic reactions.
Preparation
Preparative Methods: to a solution of MeMgCl (2.3 M, 395 mL) in diethyl ether was added dropwise allyltrichlorogermane (61 g, 0.277 mol) in nitrogen. The mixture was refluxed for 10 h. After quenching with water, the mixture was extracted with diethyl ether. Careful distillation afforded allyltrimethylgermane (68%).
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