(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]
(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Basic information
- Product Name:
- (-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]
- Synonyms:
-
- (3aS,8aR)-2-[(3aS,8aR)-3aH,8H,8aH-Indeno[1,2-d][1,3]oxazol-2-ylmethyl]-3aH,8H,8aH-indeno[1,2-d][1,3]oxazole
- [3as-[2(3′Ar*,8′As*),3′AΑ,8′AΑ]]-()-2,2′-Methylenebis[3a,8a-Dihydro-8H-Inden
- [3AS-[2(3'A R*,8'A S*),3'A-ALPHA,8'A-ALPHA]]-(-)-2,2'-METHYLENEBIS[3A,8A-DIHYDRO-8 H-INDENO[1,2-D]OXAZOLE]
- (-)-2,2'-Methylenebis
- (3aS,3′aS,8aR,8′aR)-(-)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
- Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)methane
- 8H-Indeno[1,2-d]oxazole,2,2'-Methylenebis[3a,8a-dihydro-, (3aS,3'aS,8aR,8'aR)-
- (-)-2,2'-Methylenebis[(3AS,8AR)-3A,8A-Dihydro-8H-Indeno[1,2-D]Oxazole],98%
- CAS:
- 175166-49-1
- MF:
- C21H18N2O2
- MW:
- 330.38
- Product Categories:
-
- Asymmetric Synthesis
- Synthetic Organic Chemistry
- BOX
- Chiral Catalysts, Ligands, and Reagents
- Privileged Ligands and Complexes
- BOX series
- Chiral Nitrogen
- Mol File:
- 175166-49-1.mol
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(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Chemical Properties
- Melting point:
- 224 °C
- Boiling point:
- 493.2±45.0 °C(Predicted)
- Density
- 1.48±0.1 g/cm3(Predicted)
- refractive index
- -360 ° (C=1, CH2Cl2)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- almost transparency in Dichloromethane
- form
- powder to crystal
- pka
- 5.47±0.20(Predicted)
- color
- White to Almost white
- optical activity
- [α]22/D 355°, c = 3.7 in chloroform
- InChIKey
- BDHSVQLSNIGJNC-JYWFKMLOSA-N
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(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE] Usage And Synthesis
Chemical Properties
White powder
Uses
(3aS,3′aS,8aR,8′aR)-2,2′-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole] can be used as a chiral ligand:
- In the preparation of oxazole α-hydroxy esters through intermolecular Alder-Ene reaction.
- In the atom transfer radical polymerization reactions of methyl methacrylate.
- In the copper-catalyzed synthesis of isoxazolidine derivatives by reacting nitrone with α,β-unsaturated acyl?phosphonate.
(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]Supplier
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Energy Chemical
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(-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE](175166-49-1)Related Product Information
- (3aS,3a'S,8aR,8a'R)-2,2'-(1,3-Diphenylpropane-2,2-diyl)bis(8,8a-dihydro-3aH-indeno[1,2-d]oxazole)
- (3aS,3'aS,8aR,8'aR)-2,2'-Cyclopentylidenebis[3a,8a-dihydr o-8H-indeno[1,2-d]oxazole]
- (3aR,3'aR,8aS,8'aS)-2,2'-Cyclopentylidenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
- (+)-2,2'-METHYLENEBIS[(3AR,8AS)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]
- (3aR,3'aR,8aS,8'a'S)-2,2'-cyclopropylidenebis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole
- (3aR,3a'R,8aS,8a'S)-2,2'-(1,3-diphenylpropane-2,2-diyl)bis(3a,8a-dihydro-8H-indeno[1,2-d]oxazole)
- (3aS,3'aS,8aR,8'a'R)-2,2'-cyclopropylidenebis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole
- Indene
- Trans-1-Amino-2-hydroxyindane
- 2-Indanol
- (R)-(-)-1-Aminoindan
- (1S,2R)-(-)-cis-1-Amino-2-indanol
- 2-Ethyl-2-oxazoline
- (S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)
- 1-Aminoindan
- (-)-2,2'-METHYLENEBIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]