(S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS
(S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS Basic information
- Product Name:
- (S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS
- Synonyms:
-
- (S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS
- (S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane,min.93%CTH-(S)-3,5-xylyl-PHANEPHOS
- (S)-xylyl-PHANEPHos, (S)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.24,7]hexadeca-hexaene
- S-Xylyl-Phanephos
- Tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[bis(3,5-dimethylphenyl)phosphine] stereoisomer
- (S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, Min. 97% CTH-(S)-3,5-xylyl-PHANEPHOS
- (S)-XylPhanephos
- (S)-4,12-Bis(1,1-bis(3,5-dimethylphenyl)phosphine)-[2.2]paracyclophane
- CAS:
- 325168-88-5
- MF:
- C48H50P2
- MW:
- 688.86
- Product Categories:
-
- Chiral Phosphine
- PHANEPhos Series
- organophosphine ligand
- Mol File:
- 325168-88-5.mol
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(S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS Chemical Properties
- Melting point:
- 234-238 °C
- Boiling point:
- 785.2±60.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- color
- white
- optical activity
- [α]/D +61.0°, c = 0.1 in ethanol
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(S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS Usage And Synthesis
Reaction
- Chiral ligand employed in the enantioselective hydrogenation of various ketones.
- Chiral ligand employed in the enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes.
- Chiral ligand employed in the enantioselective [2+2] cycloaddition of oxabicyclic alkenes with terminal alkynes.
- Chiral ligand employed in the gold-catalyzed enantioselective Cope rearrangement of achiral 1,5-dienes.
Uses
Efficient ligand for asymmetric hydrogenation of dehydroamino acids, methyl esters and ketones.
(S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOSSupplier
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(S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS(325168-88-5)Related Product Information
- (S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS
- TRI-M-TOLYLPHOSPHINE
- DICHLORO[(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2,2]-PARACYCLOPHANE][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM
- [2.2]Paracyclophane
- (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE
- (R)-(-)-4,12-BIS(DI-3,5-XYLYLPHOSPHINO)[2.2]PARACYCLOPHANE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
- DICHLORO[(S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)