Basic information Reaction Safety Supplier Related

DI-T-BUTYLNEOPENTYLPHONIUM TETRAFLUOROBORATE,MIN.95%

Basic information Reaction Safety Supplier Related

DI-T-BUTYLNEOPENTYLPHONIUM TETRAFLUOROBORATE,MIN.95% Basic information

Product Name:
DI-T-BUTYLNEOPENTYLPHONIUM TETRAFLUOROBORATE,MIN.95%
Synonyms:
  • ditert-butyl(2,2-dimethylpropyl)phosphanium,tetrafluoroborate
  • DI-T-BUTYLNEOPENTYLPHONIUM TETRAFLUOROBORATE,MIN.95%
  • Di-t-butylneopentylphosphoniumtetrafluoroborate,min.95%
  • Di-t-butylneopentylphosphonium tetrafluoroborate, min. 95%
  • Bis(1,1-dimethylethyl)(2,2-dimethylpropyl)phosphine tetrafluoroborate
  • 95% (t-Bu)2(C5H11)PH+BF4-
  • DI-T-BUTYLNEOPENTYLPHOSPHONIUM TETRAFLUOROBORATE,(T-BU)2(C5H11)PH+BF4-
  • Di-t-butylneopentylphosphoniuM tetrafluoroborate,95% (t-Bu)2(C5H11)PH+BF4-
CAS:
886059-84-3
MF:
C13H30BF4P
MW:
304.16
Product Categories:
  • Achiral Phosphine
  • Alkyl Phosphine
  • P-H
  • organophosphine ligand
Mol File:
886059-84-3.mol
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DI-T-BUTYLNEOPENTYLPHONIUM TETRAFLUOROBORATE,MIN.95% Chemical Properties

Melting point:
258-262°C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
solid
color 
white
InChI
1S/C13H29P.BF4/c1-11(2,3)10-14(12(4,5)6)13(7,8)9;2-1(3,4)5/h10H2,1-9H3;/q;-1/p+1
InChIKey
UWNPUGYQGIWNRI-UHFFFAOYSA-O
SMILES
F[B-](F)(F)F.CC(C)(C)C[PH+](C(C)(C)C)C(C)(C)C
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Safety Information

Hazard Codes 
Xn
Risk Statements 
21/22-36/37/38
Safety Statements 
26
WGK Germany 
3
Storage Class
11 - Combustible Solids
Hazard Classifications
Acute Tox. 4 Dermal
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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DI-T-BUTYLNEOPENTYLPHONIUM TETRAFLUOROBORATE,MIN.95% Usage And Synthesis

Reaction

  1. The phosphine, used in combination with a palladium source and base, produces a highly effective catalyst for the Buchwald- Hartwig amination of aryl bromides at room temperature.
  2. Phosphine used in the palladium-catalyzed, Suzuki cross-coupling reaction.
  3. Phosphine used in the palladium-catalyze Kumada cross-coupling reaction.

Uses

  • Cocatalyst for palladium-catalyzed Kumada couplings

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings

DI-T-BUTYLNEOPENTYLPHONIUM TETRAFLUOROBORATE,MIN.95%Supplier

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