ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Basic information
- Product Name:
- (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
- Synonyms:
-
- MANDYPHOS SL-M002-1
- (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
- (R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLA
- (S,S)-(+)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
- (R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
- (
R, R)-1,1#-Bis[ -(dimethylamino)benzyl]-(S,S)-2,2#-bis(dicyc - (S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene,min.97%
- (r,r)-1,1'-bis[(r)-α-(dimethylamino)phenylmethyl]-2,2'-bis(dicyclohexylphosphino)ferrocene (acc to cas)
- CAS:
- 494227-35-9
- MF:
- C52H72FeN2P2
- MW:
- 842.95
- Product Categories:
-
- Chiral Phosphine
- Ferrocene Series
- Mandyphos Series
- Mol File:
- 494227-35-9.mol
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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Chemical Properties
- alpha
- +54.6° (c 1.0, CHCl3)
- form
- solid
- color
- orange-red
- Stability:
- store cold
- CAS DataBase Reference
- 494227-35-9
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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Usage And Synthesis
Reaction
Ligand for a copper-catalyzed domino conjugated reduction/aldol reaction of methyl acrylate with various alkyl aryl ketones.
Ligand for asymmetric palladium-catalyzed cross-coupling of aryl triflates with [(η6-benzylamine)Cr(CO)3]
Chemical Properties
Orange powder
General Description
sold in collaboration with Solvias AG
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENESupplier
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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE(494227-35-9)Related Product Information
- (S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE
- (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE
- (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE
- (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
- (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE
- Ferrocene
- (R)-(+)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE
- (+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE
- 1,1'-DIMETHYLFERROCENE
- 1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
- 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE
- N,N-Dimethylaminomethylferrocene
- 1,1'-DIETHYLFERROCENE
- (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE