Basic information Safety Supplier Related
ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Crown ether >  4-NITROBENZO-18-CROWN-6

4-NITROBENZO-18-CROWN-6

Basic information Safety Supplier Related

4-NITROBENZO-18-CROWN-6 Basic information

Product Name:
4-NITROBENZO-18-CROWN-6
Synonyms:
  • 4'-NITROBENZO-18-CROWN-6
  • 4-NITROBENZO-18-CROWN-6
  • 4'-NITROBENZO-18-CROWN 6-ETHER
  • 2,3-(4-NITROBENZO)-1,4,7,10,13,16-HEXAOXACYCLOOCTADEC-2-ENE
  • NITROBENZO-18-CROWN-6
  • 4-Nitrobenzo-18-crown-6,99%
  • NITROBENZO-18-CROWN-6, 99+%
  • 1,16-(4-Nitro-1,2-phenylene)-1,4,7,10,13,16-hexaoxahexadecane
CAS:
53408-96-1
MF:
C16H23NO8
MW:
357.36
Product Categories:
  • Crown Ethers
  • Functional Materials
  • Macrocycles for Host-Guest Chemistry
  • Chelation/Complexation Compounds
  • Crown Ethers
  • Synthetic Reagents
Mol File:
53408-96-1.mol
More
Less

4-NITROBENZO-18-CROWN-6 Chemical Properties

Melting point:
82-86 °C
Boiling point:
453.11°C (rough estimate)
Density 
1.163
refractive index 
1.5230 (estimate)
form 
powder to crystal
color 
White to Yellow
InChI
InChI=1S/C16H23NO8/c18-17(19)14-1-2-15-16(13-14)25-12-10-23-8-6-21-4-3-20-5-7-22-9-11-24-15/h1-2,13H,3-12H2
InChIKey
LQXOKBZWNFJJGI-UHFFFAOYSA-N
SMILES
O1C2=CC=C([N+]([O-])=O)C=C2OCCOCCOCCOCCOCC1
CAS DataBase Reference
53408-96-1(CAS DataBase Reference)
More
Less

Safety Information

Hazard Codes 
Xi,C,F
Risk Statements 
36/37/38-34-11
Safety Statements 
26-36-45-36/37/39-16
WGK Germany 
3
3
HS Code 
29329985

MSDS

More
Less

4-NITROBENZO-18-CROWN-6 Usage And Synthesis

Chemical Properties

LIGHT YELLOW FLUFFY POWDER

Purification Methods

If impure and discoloured, then chromatograph it through Al2O3 and elute with *C6H6/hexane (1:1) containing 1% MeOH. The fractions are followed by TLC on Al2O3 (with Dragendorff's reagent for detection: RF 0.6 in the above solvent system). Recrystallise the residues from the required fractions from *C6H6/hexane to give yellowish leaflets. It complexes with Na or K ions with logKNa 3.95 and logKK 4.71. [Petranek & Ryba Collect Chem Czech Chem Commun 39 2033 1974.]

4-NITROBENZO-18-CROWN-6Supplier

Zhengzhou Acme Chemical Co., Ltd. Gold
Tel
0371-037163312495,13303845143 13303845143
Email
3001379618@qq.com
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Email
market03@meryer.com
Alfa Aesar
Tel
400-6106006
Email
saleschina@alfa-asia.com
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Email
Sales-CN@TCIchemicals.com