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7-OCTEN-2-OL, 2-METHYL-6-METHYLENE

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7-OCTEN-2-OL, 2-METHYL-6-METHYLENE Basic information

Product Name:
7-OCTEN-2-OL, 2-METHYL-6-METHYLENE
Synonyms:
  • MYRCENOL 50
  • 2-methyl-6-methylene-7-octen-2-o
  • 2-Methyl-6-methylene-7-octen-2-ol
  • 3-Methylene-7-methyl-1-octen-7-ol
  • 2-methyl-6-methyleneoct-7-en-2-ol
  • MYCENOL5
  • 2-Methyl-6-methylenoct-7-en-2-ol
  • 2H MYRCENOL
CAS:
543-39-5
MF:
C10H18O
MW:
154.25
EINECS:
208-843-8
Mol File:
543-39-5.mol
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7-OCTEN-2-OL, 2-METHYL-6-METHYLENE Chemical Properties

Boiling point:
217.64°C (rough estimate)
Density 
0.8389 (rough estimate)
refractive index 
1.4666 (estimate)
pka
15.30±0.29(Predicted)
Odor
at 100.00 %. fresh floral lavender citrus
Odor Type
floral
LogP
2.613 (est)
EPA Substance Registry System
7-Octen-2-ol, 2-methyl-6-methylene- (543-39-5)
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7-OCTEN-2-OL, 2-METHYL-6-METHYLENE Usage And Synthesis

Chemical Properties

It is a colorless liquid with a fresh, floral, slightly lime-like odor. Due to its conjugated double bonds, it tends to polymerize; polymerization can be suppressed by adding inhibitors (e.g., antioxidants such as BHT).
Myrcenol can be prepared by treating myrcene with diethylamine to give a mixture of geranyl- and neryldiethylamine. These compounds are hydrated with a dilute acid to the corresponding hydroxydiethylamines. Deamination tomyrcenol is effected by using a palladium–phosphine–cation complex as a catalyst.
Myrcenol is used in perfumery to obtain a lifting top note in citrus and lavender compositions. It is mainly important in the production of 4-(4-hydroxy-4- methylpentyl)-3-cyclohexenecarboxaldehyde.

Definition

ChEBI: A monoterpenoid that is oct-7-en-2-ol substituted by a methyl group at position 2 and a methylidene group at position 6 respectively.

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