TRIPHENYL TRITHIOORTHOFORMATE Chemical Properties

Melting point:

39-41 °C (lit.)

Boiling point:

488.1±25.0 °C(Predicted)

Density 

1.26±0.1 g/cm3(Predicted)

Flash point:

>230 °F

pka

23(at 25℃)

form 

powder to crystal

color 

White to Almost white

BRN 

1914230

InChIKey

YOQHDHPBEXTHCP-UHFFFAOYSA-N

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-37/39

RIDADR 

UN 3335

WGK Germany 

3

F 

13

HS Code 

29309090

MSDS

• Language:English Provider:SigmaAldrich

TRIPHENYL TRITHIOORTHOFORMATE Usage And Synthesis

Uses

Tris(phenylthio)methane has been used in the preparation of:

• 1-phenylthio-tetrahydroisoquinolines via activated Pictet-Spengler cyclization
• homoallylchalcogenoacetals via reaction with allylsilanes in the presence of a Lewis acid

Uses

A precursor to tris(phenylthio)methyllithium, used for nucleophilic carboxylation; electrophilic formylating agent for aromatic compounds and diazo esters.

storage

Tris(phenylthio)Methane ?is stable indefinitely if stored at ambient temperatures in tightly sealed containers to exclude moisture, which promotes hydrolysis to thiophenol and formic acid.

TRIPHENYL TRITHIOORTHOFORMATE(4832-52-4)Related Product Information

• 2,4,6-TRIS(PERFLUOROETHYL)-S-TRIAZINE
• TRIS(2-METHOXYPHENYL)PHOSPHINE
• 2,4,6-Tris(trifluoromethyl)-1,3,5-triazine
• TRIS(ETHYLTHIO)METHANE
• Tris(trimethylsilyloxy)ethylene
• Methylene dithiocyanate
• TRIPHENYL TRITHIOORTHOFORMATE
• BIS(PHENYLTHIO)METHANE
• TRIS(METHYLTHIO)METHANE