Methyl nitroacetate Chemical Properties

Boiling point:

195-198 °C (lit.)

Density 

1.294 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.425(lit.)

Flash point:

221 °F

storage temp. 

Keep in dark place,Sealed in dry,Room Temperature

solubility 

Miscible with ethanol, ether and most organic solvents.

form 

clear liquid

pka

5.73±0.29(Predicted)

color 

Colorless to Light yellow

Sensitive 

Light Sensitive

BRN 

1758670

InChIKey

ALBSWLMUHHZLLR-UHFFFAOYSA-N

CAS DataBase Reference

2483-57-0(CAS DataBase Reference)

NIST Chemistry Reference

Acetic acid, nitro-, methyl ester(2483-57-0)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36-37/39

WGK Germany 

2

RTECS 

AJ1093000

F 

8

HS Code 

29161995

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

Methyl nitroacetate Usage And Synthesis

Chemical Properties

clear yellow liquid

Uses

Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.

Synthesis Reference(s)

The Journal of Organic Chemistry, 25, p. 266, 1960 DOI: 10.1021/jo01072a606

Methyl nitroacetate(2483-57-0)Related Product Information

• Methyl acetate
• Methyl glycolate
• Methylparaben
• Acetonitrile
• Methyl bromoacetate
• Methyl phenylacetate
• Basic Violet 1
• Methyl cyanoacetate
• Methyl methoxyacetate
• Methanol
• Diethyl nitromalonate
• Ethyl nitroacetate
• Methyl acrylate
• Paraquat dichloride
• Kresoxim-methyl
• DIETHYL SUBERATE
• Methyl
• 4-CHLORO-3-NITROCOUMARIN