Basic information Safety Supplier Related
ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Nitro compounds >  Methyl nitroacetate

Methyl nitroacetate

Basic information Safety Supplier Related

Methyl nitroacetate Basic information

Product Name:
Methyl nitroacetate
Synonyms:
  • NITROACETIC ACID METHYL ESTER
  • Methyl 2-nitroacetate
  • Methyl a-nitroacetate
  • methyl2-nitroacetate
  • nitro-aceticacimethylester
  • METHYL ALFA NITROACETATE
  • METHYL NITROACETATE
  • Methylnitroacetate,98%
CAS:
2483-57-0
MF:
C3H5NO4
MW:
119.08
EINECS:
219-622-0
Product Categories:
  • Acetics acid and esters
  • Acids and Derivatives
  • C2 to C5
  • Carbonyl Compounds
  • Esters
Mol File:
2483-57-0.mol
More
Less

Methyl nitroacetate Chemical Properties

Boiling point:
195-198 °C (lit.)
Density 
1.294 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.425(lit.)
Flash point:
221 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Miscible with ethanol, ether and most organic solvents.
form 
clear liquid
pka
5.73±0.29(Predicted)
color 
Colorless to Light yellow
Sensitive 
Light Sensitive
BRN 
1758670
InChI
InChI=1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3
InChIKey
ALBSWLMUHHZLLR-UHFFFAOYSA-N
SMILES
C(OC)(=O)C[N+]([O-])=O
CAS DataBase Reference
2483-57-0(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, nitro-, methyl ester(2483-57-0)
More
Less

Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
2
RTECS 
AJ1093000
8
HS Code 
29161995

MSDS

More
Less

Methyl nitroacetate Usage And Synthesis

Chemical Properties

clear yellow liquid

Uses

Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.

Synthesis Reference(s)

The Journal of Organic Chemistry, 25, p. 266, 1960 DOI: 10.1021/jo01072a606

Methyl nitroacetateSupplier

Shanghai hanchen new material technology co., ltd Gold
Tel
13564554711
Email
26639560@qq.com
Shandong Laifu Technology Development Co., Ltd. Gold
Tel
0531-18053119814 18053119814
Email
1375993372@qq.com
Accela ChemBio Co.,Ltd. Gold
Tel
021-50795510 4000665055
Email
SY06@accelachem.com
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com
PharmaBlock Sciences (Nanjing),Inc.
Tel
025-86918202 4000255188
Email
sales@pharmablock.com