ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Nitro compounds > Methyl nitroacetate
Methyl nitroacetate
Methyl nitroacetate Basic information
- Product Name:
- Methyl nitroacetate
- Synonyms:
-
- NITROACETIC ACID METHYL ESTER
- Methyl 2-nitroacetate
- Methyl a-nitroacetate
- methyl2-nitroacetate
- nitro-aceticacimethylester
- METHYL ALFA NITROACETATE
- METHYL NITROACETATE
- Methylnitroacetate,98%
- CAS:
- 2483-57-0
- MF:
- C3H5NO4
- MW:
- 119.08
- EINECS:
- 219-622-0
- Product Categories:
-
- Acetics acid and esters
- Acids and Derivatives
- C2 to C5
- Carbonyl Compounds
- Esters
- Mol File:
- 2483-57-0.mol
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Methyl nitroacetate Chemical Properties
- Boiling point:
- 195-198 °C (lit.)
- Density
- 1.294 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.425(lit.)
- Flash point:
- 221 °F
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Miscible with ethanol, ether and most organic solvents.
- form
- clear liquid
- pka
- 5.73±0.29(Predicted)
- color
- Colorless to Light yellow
- Sensitive
- Light Sensitive
- BRN
- 1758670
- InChI
- InChI=1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3
- InChIKey
- ALBSWLMUHHZLLR-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C[N+]([O-])=O
- CAS DataBase Reference
- 2483-57-0(CAS DataBase Reference)
- NIST Chemistry Reference
- Acetic acid, nitro-, methyl ester(2483-57-0)
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Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-37/39
- WGK Germany
- 2
- RTECS
- AJ1093000
- F
- 8
- HS Code
- 29161995
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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Methyl nitroacetate Usage And Synthesis
Chemical Properties
clear yellow liquid
Uses
Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.
Synthesis Reference(s)
The Journal of Organic Chemistry, 25, p. 266, 1960 DOI: 10.1021/jo01072a606
Methyl nitroacetateSupplier
Shanghai hanchen new material technology co., ltd Gold
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- 13564554711
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Shandong Laifu Technology Development Co., Ltd. Gold
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- 0531-18053119814 18053119814
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Accela ChemBio Co.,Ltd. Gold
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- 021-50795510 4000665055
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J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
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PharmaBlock Sciences (Nanjing),Inc.
- Tel
- 025-86918202 4000255188
- sales@pharmablock.com
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Methyl nitroacetate(2483-57-0)Related Product Information
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- Methyl glycolate
- Methylparaben
- Acetonitrile
- Methyl bromoacetate
- Methyl phenylacetate
- Basic Violet 1
- Methyl cyanoacetate
- Methyl methoxyacetate
- Methanol
- Diethyl nitromalonate
- Ethyl nitroacetate
- Methyl acrylate
- Paraquat dichloride
- Kresoxim-methyl
- DIETHYL SUBERATE
- Methyl
- 4-CHLORO-3-NITROCOUMARIN