4-NITROTHIOANISOLE Chemical Properties

Melting point:

66-69 °C (lit.) 68-72 °C (lit.)

Boiling point:

140 °C / 2mmHg

Density 

1.2391

refractive index 

1.6401 (estimate)

storage temp. 

Sealed in dry,Room Temperature

solubility 

soluble in Toluene

form 

powder to crystal

color 

Light yellow to Yellow to Orange

Sensitive 

Stench

BRN 

1817928

CAS DataBase Reference

701-57-5(CAS DataBase Reference)

NIST Chemistry Reference

Methyl 4-nitrophenyl sulphide(701-57-5)

Safety Information

Hazard Codes 

Xi

Risk Statements 

20/21/22

Safety Statements 

22-36/37/39-36/37

WGK Germany 

3

Hazard Note 

Harmful/Stench

HazardClass 

IRRITANT, STENCH

HS Code 

29309090

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

4-NITROTHIOANISOLE Usage And Synthesis

Chemical Properties

Yellow solid

Uses

4-Nitrothioanisole may be used to synthesize 4-nitrothioanisole sulfoxide and methyl 4-nitrophenyl sulfoxide.

Synthesis Reference(s)

Tetrahedron Letters, 24, p. 2575, 1983 DOI: 10.1016/S0040-4039(00)81985-1

General Description

4-Nitrothioanisole in acetone-d₆ solution exhibits twofold barrier to rotation about the Csp²-S bond as 16.1±1.5kJ/mol. 4-Nitrothioanisole undergoes hydrogenation in the presence of sulfided Pd/C catalysts.

4-NITROTHIOANISOLE(701-57-5)Related Product Information

• 4-Nitrophenylacetic acid
• 4-Nitrobenzonitrile
• Ethyl 4-nitrophenylacetate
• 4-Nitrobenzoic acid
• 2-CHLORO-5-NITROBENZENESULFONIC ACID
• 4-CHLORO-4'-NITRODIPHENYL SULPHONE
• 2-NITRO-5-THIOCYANATOBENZOIC ACID
• BIS(4-NITROPHENYL) SULFONE
• 4-(Trifluoromethylthio)nitrobenzene
• 4-NITRODIPHENYL SULFONE
• 2,4-DINITROPHENYL THIOCYANATE
• 2-AMINO-5-(4-NITROPHENYLSULFONYL)THIAZOLE
• BIS(4-NITROPHENYL) SULFIDE
• 4-AMINO-4'-NITRODIPHENYL SULFIDE
• 4-NITROPHENYL PHENYL SULFIDE
• 4-BROMO-3-NITROTHIOANISOLE
• 3-NITROTHIOANISOLE / METHYL 3-NITROPHENYL SULPHIDE
• 4-BROMO-3-NITROTHIOANISOLE