(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Chemical Properties

Melting point:

330-332 °C(lit.)

alpha 

D23 +580° (c = 0.01 in ethanol)

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

form 

Liquid May Develop Some Turbidity or Precipitate

color 

Light yellow to gold to brown

λmax

509nm(CH2Cl2)(lit.)

Merck 

14,5252

InChIKey

LJVAWOSDJSQANR-OHRASPNLSA-K

SMILES

C12O[Mn](Cl)OC3=C(C=N[C@@H]4CCCC[C@H]4N=CC1=CC(C(C)(C)C)=CC=2C(C)(C)C)C=C(C(C)(C)C)C=C3C(C)(C)C |t:7,16,&1:9,14,r|

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38-20/21/22

Safety Statements 

26-36-36/37/39

WGK Germany 

3

F 

9

HS Code 

29349990

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Usage And Synthesis

Chemical Properties

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE is Dark brown powder or chunks

Uses

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE is a coordinated compound of manganese and a salen-type ligand. It is also used as an asymmetric catalyst used to enantioselectively transform prochiral alkenes into epoxides.

Uses

Chiral catalyst for epoxidation of olefins.

Uses

Salen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins. High enantioselectivities and yields are obtained for a variety of substrates, especially cis-alkenes. A few applications include the synthesis of the taxol side chain and cis-1-amino-2-indanol. Jacobsen′s catalyst has also been used in the asymmetric α-hydroxylation of silyl enol ethers. Catalyst for the enantioselective epoxidation of a variety of olefins.

Reactions

1. Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.
2. Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corresponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
3. symmetric Kinetic resolution of secondary alcohols in water.
4. Enantioselective Reformatsky reaction with ketones.

General Description

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) is a chiral compound used as a catalytic reagent.

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE(138124-32-0)Related Product Information

• (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
• (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
• (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
• (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
• N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE
• (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
• Manganese
• Manganese chloride tetrahydrate
• (R,R)-(-)-1,2-DIAMINOCYCLOHEXANE HYDROCHLORIDE
• CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE
• N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE
• N-benzylidenecyclohexylamine
• N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE