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2,4-DIBROMO-2,4-DIMETHYL-3-PENTANONE

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2,4-DIBROMO-2,4-DIMETHYL-3-PENTANONE Basic information

Product Name:
2,4-DIBROMO-2,4-DIMETHYL-3-PENTANONE
Synonyms:
  • 2,4-DIBROMO-2,4-DIMETHYL-3-PENTANONE 98%
  • 2,4-DIBROMO-2,4-DIMETHYL-3-PENTANONE, 99 %
  • 2,4-Dibromo-2,4-dimethyl-3-pentanone,98%
  • 2,4-DIBROMO-2,4-DIMETHYL-3-PENTANONE
  • 2,4-DIBROMO-2,4-DIMETHYLPENTAN-3-ONE
  • 3-Pentanone, 2,4-dibromo-2,4-dimethyl-
CAS:
17346-16-6
MF:
C7H12Br2O
MW:
271.98
Product Categories:
  • C7 to C8
  • Carbonyl Compounds
  • Ketones
Mol File:
17346-16-6.mol
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2,4-DIBROMO-2,4-DIMETHYL-3-PENTANONE Chemical Properties

Boiling point:
89-91 °C13 mm Hg(lit.)
Density 
1.61 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.506(lit.)
Flash point:
163 °F
storage temp. 
Flammables area
BRN 
1754205
CAS DataBase Reference
17346-16-6
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-27-36/37/39
RIDADR 
3334
WGK Germany 
3
HazardClass 
9
HS Code 
29147000

MSDS

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2,4-DIBROMO-2,4-DIMETHYL-3-PENTANONE Usage And Synthesis

Chemical Properties

clear colorless to amber liquid

Uses

2,4-Dibromo-2,4-dimethyl-3-pentanone may be used in the synthesis of 2-dimethylamino-4-methylene-1,3-dioxolanes, via debromination using zinc-copper couple in dimethylformamide and dimethylacetamide.

General Description

2,4-Dibromo-2,4-dimethyl-3-pentanone is an α,α′-dibromoketone. Electroreduction of 2,4-dibromo-2,4-dimethyl-3-pentanone in polar aprotic solvent has been reported. Electrochemical reduction of 2,4-dibromo-2,4-dimethyl-3-pentanone in acetic acid and sodium actetate yields α-acetoxy ketones. 2,4-Dibromo-2,4-dimethyl-3-pentanone reacts with lithium dimethylcuprate(I) in diethyl ether at -78°C to yield 2,2,4-trimethyl-3-pentanone (an α methyl ketone).

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