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Dimethylphenylsilane

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Dimethylphenylsilane Basic information

Product Name:
Dimethylphenylsilane
Synonyms:
  • SODIUM ACETATE BUFFER
  • SODIUM ACETATE ACETIC ACID
  • SODIUM ACETATE ACETIC ACID BUFFER
  • PHENYLDIMETHYLSILANE
  • ACETATE BUFFER SOLUTION TYPE 'C'
  • ACETATE BUFFER TS
  • ACETATE BUFFER SOLUTION R-455
  • FEMA 3900
CAS:
766-77-8
MF:
C8H12Si
MW:
136.27
EINECS:
212-170-5
Product Categories:
  • Reduction
  • Si (Classes of Silicon Compounds)
  • Si-H Compounds
  • Silicon Compounds (for Synthesis)
  • Synthetic Organic Chemistry
Mol File:
766-77-8.mol
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Dimethylphenylsilane Chemical Properties

Melting point:
323-329 °C(lit.)
Boiling point:
157 °C744 mm Hg(lit.)
Density 
0.889 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.497(lit.)
Flash point:
95 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
sol common organic solvent such as chloroform, 1,2- dichloroethane, benzene, ether, acetone, dioxane, THF; insol H2O.
form 
solid
color 
Colorless to Almost colorless
Specific Gravity
0.889
Water Solubility 
Not miscible in water.
Hydrolytic Sensitivity
3: reacts with aqueous base
BRN 
2204906
InChIKey
ZISUALSZTAEPJH-UHFFFAOYSA-N
CAS DataBase Reference
766-77-8(CAS DataBase Reference)
EPA Substance Registry System
Silane, dimethylphenyl- (766-77-8)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
10-36
Safety Statements 
26-36/39-24/25
RIDADR 
UN 1993 3/PG 3
WGK Germany 
1
RTECS 
AJ4375000
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29319090

MSDS

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Dimethylphenylsilane Usage And Synthesis

Chemical Properties

Clear colorless liquid

Physical properties

bp 157 °C/744 mmHg; d 0.889 g cm?3.

Uses

Diastereoselective Reduction of Carbonyl Compounds.
Hydrosilylation. With a transition metal catalyst, the hydrosilane adds to carbon–carbon double or triple bonds to give alkylsilanes or alkenylsilanes.
Hydrosilylating reagent; reductant in combination with acid or F?).

Uses

Dimethylphenylsilane is a reagent for enol ether synthesis. It acts as a catalyst. Also used as a precursor in Optical Emission Spectroscopy of Plasma Deposition Processes. It can react with vinylbenzene to produce (b-Phenyl-ethyl)-dimethylphenyl-silan.

Application

Used to reduce α-amino ketones to aminoethanols withhigh stereoselectivity. Used in the fluoride ion-catalyzedreduction of aldehydes and ketones, and α-substitutedalkanones to threo products. Erythro reduction of α-substituted alkanones to diols and aminoethanols. Together with CuCl reduces aryl ketones, but not dialkylketones. Used in the silylformylation of acetylenes.Excellent reducing agent for the reduction of enones tosaturated ketones. Shows better selectivity than LAH inthe reduction of oximes to alkoxyamines.

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