Dimethylphenylsilane
Dimethylphenylsilane Basic information
- Product Name:
- Dimethylphenylsilane
- Synonyms:
-
- SODIUM ACETATE BUFFER
- SODIUM ACETATE ACETIC ACID
- SODIUM ACETATE ACETIC ACID BUFFER
- PHENYLDIMETHYLSILANE
- ACETATE BUFFER SOLUTION TYPE 'C'
- ACETATE BUFFER TS
- ACETATE BUFFER SOLUTION R-455
- FEMA 3900
- CAS:
- 766-77-8
- MF:
- C8H12Si
- MW:
- 136.27
- EINECS:
- 212-170-5
- Product Categories:
-
- Reduction
- Si (Classes of Silicon Compounds)
- Si-H Compounds
- Silicon Compounds (for Synthesis)
- Synthetic Organic Chemistry
- Mol File:
- 766-77-8.mol
Dimethylphenylsilane Chemical Properties
- Melting point:
- 323-329 °C(lit.)
- Boiling point:
- 157 °C744 mm Hg(lit.)
- Density
- 0.889 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.497(lit.)
- Flash point:
- 95 °F
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- sol common organic solvent such as chloroform, 1,2- dichloroethane, benzene, ether, acetone, dioxane, THF; insol H2O.
- form
- solid
- color
- Colorless to Almost colorless
- Specific Gravity
- 0.889
- Water Solubility
- Not miscible in water.
- Hydrolytic Sensitivity
- 3: reacts with aqueous base
- BRN
- 2204906
- InChIKey
- ZISUALSZTAEPJH-UHFFFAOYSA-N
- CAS DataBase Reference
- 766-77-8(CAS DataBase Reference)
- EPA Substance Registry System
- Silane, dimethylphenyl- (766-77-8)
Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 10-36
- Safety Statements
- 26-36/39-24/25
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 1
- RTECS
- AJ4375000
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29319090
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
Dimethylphenylsilane Usage And Synthesis
Chemical Properties
Clear colorless liquid
Physical properties
bp 157 °C/744 mmHg; d 0.889 g cm?3.
Uses
Diastereoselective Reduction of Carbonyl Compounds.
Hydrosilylation. With a transition metal catalyst, the
hydrosilane adds to carbon–carbon double or triple bonds to
give alkylsilanes or alkenylsilanes.
Hydrosilylating reagent; reductant in combination with acid
or F?).
Uses
Dimethylphenylsilane is a reagent for enol ether synthesis. It acts as a catalyst. Also used as a precursor in Optical Emission Spectroscopy of Plasma Deposition Processes. It can react with vinylbenzene to produce (b-Phenyl-ethyl)-dimethylphenyl-silan.
Application
Used to reduce α-amino ketones to aminoethanols withhigh stereoselectivity. Used in the fluoride ion-catalyzedreduction of aldehydes and ketones, and α-substitutedalkanones to threo products. Erythro reduction of α-substituted alkanones to diols and aminoethanols. Together with CuCl reduces aryl ketones, but not dialkylketones. Used in the silylformylation of acetylenes.Excellent reducing agent for the reduction of enones tosaturated ketones. Shows better selectivity than LAH inthe reduction of oximes to alkoxyamines.
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Dimethylphenylsilane(766-77-8)Related Product Information
- Chlorodimethylpentafluorophenylsilane
- Triphenylsilane
- DIPHENYLMETHYLSILANE
- Chlorodiphenylmethylsilane
- P-TOLYLTRIMETHYLSILANE
- AMINODIMETHYLPENTAFLUOROPHENYLSILANE
- Dimethylphenylsilane
- Chlorodimethylphenylsilane
- Tetraphenylsilane
- DIMETHYL(PENTAFLUOROPHENYL)SILANE
- tert-Butylchlorodiphenylsilane
- Triphenylsilyl chloride
- PHENYLTRIMETHYLSILANE
- Triphenylsilanol
- HEXAPHENYLDISILOXANE
- 1,4-Bis(trimethylsilyl)benzene
- 1,3-BIS(TRIMETHYLSILYL)BENZENE
- SODIUM ACETATE BUFFER SOLUTION,SODIUM ACETATE BUFFER