[1R-(endo,anti)]-3-bromo-2-oxobornane-8-sulphonic acid
[1R-(endo,anti)]-3-bromo-2-oxobornane-8-sulphonic acid Basic information
- Product Name:
- [1R-(endo,anti)]-3-bromo-2-oxobornane-8-sulphonic acid
- Synonyms:
-
- [1R-(endo,anti)]-3-bromo-2-oxobornane-8-sulphonic acid
- (1R)-(+)-3-ENDO-BROMOCAMPHOR-8-SULFONIC ACID 1-HYDRATE FOR THE RESOLUTION OF RACEMATES
- (1R,4S,7-anti)-3β-Bromo-1,7-dimethyl-2-oxobicyclo[2.2.1]heptane-7-methanesulfonic acid
- (+)-3-BroMo-8-caMphorsulfonic Acid
- Bicyclo[2.2.1]heptane-7-methanesulfonic acid, 2-bromo-4,7-dimethyl-3-oxo-, (1S,2S,4R,7R)-
- (+)-3-Bromo-8-camphorsulfonic Acid
- CAS:
- 5344-58-1
- MF:
- C10H15BrO4S
- MW:
- 311.19
- EINECS:
- 2262895
- Product Categories:
-
- Chiral Reagents, Sulfur & Selenium Compounds
- Mol File:
- 5344-58-1.mol
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[1R-(endo,anti)]-3-bromo-2-oxobornane-8-sulphonic acid Chemical Properties
- Melting point:
- >96°C (dec.)
- Density
- 1.647±0.06 g/cm3(Predicted)
- storage temp.
- Hygroscopic, -20°C Freezer, Under inert atmosphere
- solubility
- Methanol (Slightly), Water (Slightly)
- pka
- 1.53±0.50(Predicted)
- form
- Solid
- color
- Pale Beige to Light Beige
- Stability:
- Hygroscopic
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[1R-(endo,anti)]-3-bromo-2-oxobornane-8-sulphonic acid Usage And Synthesis
Chemical Properties
[1R-(endo,anti)]-3-bromo-2-oxobornane-8-sulphonic acid is off-white Solid
Uses
[1R-(endo,anti)]-3-bromo-2-oxobornane-8-sulphonic acid is a chiral reagent used in optical resolution.
Purification Methods
Crystallise the acid from water. The ammonium salt has m 268-207o, []D +81.9o (c 2.2, H2O). [Kauffman J Prakt Chem 33 95 1966.] 1R(endo, anti)-3-Bromocamphor-8-sulfonic acid ammonium salt See entry in “Metal-organic compounds”, Chapter 5.
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