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1H,1H,2H,2H-Perfluorodecyltriethoxysilane

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1H,1H,2H,2H-Perfluorodecyltriethoxysilane Basic information

Product Name:
1H,1H,2H,2H-Perfluorodecyltriethoxysilane
Synonyms:
  • PERFLUOROALKYLTRIETHOXYSILANE
  • TRIETHOXY-1H,1H,2H,2H-PERFLUORODECYLSILANE
  • 1H,1H,2H,2H-PERFLUORODECYLTRIETHOXYSILANE
  • (HEPTADECAFLUORO-1,1,2,2-TETRAHYDRODECYL)TRIETHOXYSILANE
  • (HEPTADECAFLUORO-1,1,2,2-TETRAHYDRODECYL)-1-TRIETHOXYSILANE
  • 1H,1H,2H,2H-Perfluorodecyltriethoxysilane 97%
  • 1H,1H,2H,2H-Perfluorodecyltriethoxysilane97%
  • (Heptadecafluoro-1,1,2,2-tetrahydrodecyl)triethoxysilane? Perfluorodecyltriethoxysilane
CAS:
101947-16-4
MF:
C16H19F17O3Si
MW:
610.38
EINECS:
000-000-0
Product Categories:
  • silicone additives
Mol File:
101947-16-4.mol
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1H,1H,2H,2H-Perfluorodecyltriethoxysilane Chemical Properties

Boiling point:
209-230 °C
Density 
1.389 g/mL at 25 °C
refractive index 
n20/D 1.342
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Miscible with ethanol and tetrahydrofuran.
form 
liquid
Specific Gravity
1.41
color 
Colourless
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Sensitive 
Moisture Sensitive
InChI
InChI=1S/C16H19F17O3Si/c1-4-34-37(35-5-2,36-6-3)8-7-9(17,18)10(19,20)11(21,22)12(23,24)13(25,26)14(27,28)15(29,30)16(31,32)33/h4-8H2,1-3H3
InChIKey
MLXDKRSDUJLNAB-UHFFFAOYSA-N
SMILES
[Si](OCC)(OCC)(OCC)CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
CAS DataBase Reference
101947-16-4(CAS DataBase Reference)
EPA Substance Registry System
1H,1H,2H,2H-Perfluorodecyltriethoxysilane (101947-16-4)
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Safety Information

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 1760 8/PG 3
WGK Germany 
3
Hazard Note 
Corrosive
TSCA 
No
HazardClass 
8
HS Code 
29319090

MSDS

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1H,1H,2H,2H-Perfluorodecyltriethoxysilane Usage And Synthesis

Description

1H,1H,2H,2H-Perfluorodecyltriethoxysilane, also named perfluoroalkylethyltrimethoxysilane (PFATES), is used to bond poly(tetrafluoroethylene) films to silicon wafers and it is also utilized in anti-reflective coating, release coating and soil repellent coating because of its special chemical structure. It can be used as an anti-fingerprint agent for glass products such as advanced mobile phone screens and camera lenses.

Chemical Properties

Colorless liquid

Uses

1H,1H,2H,2H-Perfluorodecyltriethoxysilane is used in making thin film transistors, polyethersulfone membranes, and a superwettable Janus membrane.

Application

1H,1H,2H,2H-Perfluorodecyltriethoxysilane(PFDTES) was used to functionalize hydrophobic ceramic membranes with nanosized pores. It was also used to functionalize Cu2(OH)3NO3 crystal to render it hydrophobic. The product may be used to coat nanosized medical devices.
PFDTES is used for the superhydrophobicity of polyvinylidene fluoride(PVDF) to protect the metal surfaces from fouling. A cost effective and scalable superamphiphobic spray coating of PFDTES on stainless steel surfaces may potentially be used to create anti-icing and stain-resistant surfaces. It may be used to modify the surface of poly(methyl methacrylate(PMMA) for the fabrication of microfluidic chips.

General Description

1H,1H,2H,2H-Perfluorodecyltriethoxysilane(PFDTES) is a fluoroalkylsilanes(FAS) with low surface energy and high wettability due to the presence of fluorinated carbons. It is used as a superhydrophobic agent for synthesizing various functional coatings.

Synthesis

1H,1H,2H,2H-Perfluorodecyltriethoxysilane could be synthesized through the reaction of perfluorooctylethylene with triethoxysilane. The volatile matter is removed by distillation under reduced pressure. Finally, after purification,1H,1H,2H,2H-Perfluorodecyltriethoxysilane with a purity of 99% is obtained. The yield can reach 97.3%.

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