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ALLYL PHENYL SULFIDE

Basic information Safety Supplier Related

ALLYL PHENYL SULFIDE Basic information

Product Name:
ALLYL PHENYL SULFIDE
Synonyms:
  • ALLYL PHENYL SULFIDE
  • ALLYL PHENYL SULPHIDE
  • (Allylsulfanyl)benzene
  • (Allylthio)benzene
  • 3-(Phenylthio)prop-1-ene
  • 3-(Phenylthio)propene
  • Allyl phenyl thioether
  • Benzene, (2-propenylthio)-
CAS:
5296-64-0
MF:
C9H10S
MW:
150.24
EINECS:
226-142-5
Product Categories:
  • Building Blocks
  • Chemical Synthesis
  • Organic Building Blocks
  • Sulfides/Disulfides
  • Organic Building Blocks
  • Sulfur Compounds
  • Sulfur Compounds
Mol File:
5296-64-0.mol
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ALLYL PHENYL SULFIDE Chemical Properties

Melting point:
-48--46.5 °C
Boiling point:
223-225 °C(lit.)
Density 
1.024 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.572
Flash point:
>98°C
form 
clear liquid
color 
Colorless to Almost colorless
Sensitive 
Air Sensitive
BRN 
1856940
LogP
3.510
CAS DataBase Reference
5296-64-0(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21
Safety Statements 
23-36/37/39
RIDADR 
UN 2810 6.1/PG 2
WGK Germany 
3
RTECS 
WR2400000
13
HS Code 
2930.90.2900
HazardClass 
6.1(b)
PackingGroup 
III

MSDS

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ALLYL PHENYL SULFIDE Usage And Synthesis

Synthesis Reference(s)

Synthesis, p. 625, 1984
Tetrahedron, 47, p. 8621, 1991 DOI: 10.1016/S0040-4020(01)82405-4
Tetrahedron Letters, 20, p. 1481, 1979

Purification Methods

Dissolve the sulfide in Et2O, wash with alkali, H2O, dry over CaCl2, evaporate and fractionally distil it, preferably under vacuum. It should not give a precipitate with an alcoholic solution of Pb(OAc)2. [Hurd & Greengard J Am Chem Soc 52 3356 1930, Tarbell & McCall J Am Chem Soc 74 48 1952, Beilstein 6 IV 1479.]

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