ALLYL PHENYL SULFIDE Chemical Properties

Melting point:

-48--46.5 °C

Boiling point:

223-225 °C(lit.)

Density 

1.024 g/mL at 20 °C(lit.)

refractive index 

n20/D 1.572

Flash point:

>98°C

solubility 

insol water; sol most organic solvents

form 

clear liquid

color 

Colorless to Almost colorless

Sensitive 

Air Sensitive

BRN 

1856940

LogP

3.510

CAS DataBase Reference

5296-64-0(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xn

Risk Statements 

20/21

Safety Statements 

23-36/37/39

RIDADR 

UN 2810 6.1/PG 2

WGK Germany 

3

RTECS 

WR2400000

F 

13

HS Code 

2930.90.2900

HazardClass 

6.1(b)

PackingGroup 

III

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

ALLYL PHENYL SULFIDE Usage And Synthesis

Synthesis Reference(s)

Synthesis, p. 625, 1984
Tetrahedron, 47, p. 8621, 1991 DOI: 10.1016/S0040-4020(01)82405-4
Tetrahedron Letters, 20, p. 1481, 1979

Purification Methods

Dissolve the sulfide in Et2O, wash with alkali, H2O, dry over CaCl2, evaporate and fractionally distil it, preferably under vacuum. It should not give a precipitate with an alcoholic solution of Pb(OAc)2. [Hurd & Greengard J Am Chem Soc 52 3356 1930, Tarbell & McCall J Am Chem Soc 74 48 1952, Beilstein 6 IV 1479.]

Preparation and handling

ALLYL PHENYL SULFIDE can be made from Allyl Bromide and sodium thiophenolate in ethanol.
Handling, Storage, and Precautions: must be handled in a fume hood due to stench caused by  contamination with Thiophenol. The pure sulfide has a more agreeable odor with a sweet overtone. No  special precautions are necessary when handling in the atmosphere for weighing and transferring. In order  to avoid autoxidation the sulfide should be stored in a well sealed vessel with exclusion of oxygen and moisture at 4 °C.

ALLYL PHENYL SULFIDE(5296-64-0)Related Product Information

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