3,5-DI-TERT-BUTYL-O-BENZOQUINONE
3,5-DI-TERT-BUTYL-O-BENZOQUINONE Basic information
- Product Name:
- 3,5-DI-TERT-BUTYL-O-BENZOQUINONE
- Synonyms:
-
- 3,5-di-tert-Butyl-ortho-benzoquinone
- o-Benzoquinone, 3,5-di-tert-butyl-
- Dibutylbenzoquinone
- 3,5-Cyclohexadiene-1,2-dione, 3,5-bis(1,1-dimethylethyl)-
- 3,5-Di-tert-butylbenzoquinone, 98+%
- 3,5-Di-tert-butyl-1,2-benzenedione
- 3,5-Ditert-butyl-3,5-cyclohexadiene-1,2-dione
- 4,6-Ditert-butyl-3,5-cyclohexadiene-1,2-dione
- CAS:
- 3383-21-9
- MF:
- C14H20O2
- MW:
- 220.31
- EINECS:
- 222-189-0
- Product Categories:
-
- Anthraquinones, Hydroquinones and Quinones
- C13 to C14
- Carbonyl Compounds
- Ketones
- Mol File:
- 3383-21-9.mol
3,5-DI-TERT-BUTYL-O-BENZOQUINONE Chemical Properties
- Melting point:
- 112-114 °C(lit.)
- Boiling point:
- 321.25°C (rough estimate)
- Density
- 1.0106 (rough estimate)
- refractive index
- 1.4970 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Chloroform (Sparingly), Methanol (Very Slightly)
- form
- Solid
- color
- Very Dark Green to Very Dark Brown
- BRN
- 2047944
- Stability:
- Stable. Incompatible with reducing agents, strong oxidizing agents.
- CAS DataBase Reference
- 3383-21-9(CAS DataBase Reference)
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
3,5-DI-TERT-BUTYL-O-BENZOQUINONE Usage And Synthesis
Chemical Properties
dark red crystals or powder
Uses
3,5-Di-tert-butyl-o-benzoquinone was used in the preparation of benzoxazoles derivative ligands. It was also used in the preparation of 1,4-benzodioxines via hetero Diels Alder reaction with acyclic dienes.
Uses
4,6-Di-tert-butyl-1,2-benzoquinone is a Ortho-Quinone derivative is know to possess a number of biological properties such as antitumoral, antimicrobacterial and anti-cardiovascular disease.
Synthesis Reference(s)
Tetrahedron, 44, p. 6397, 1988 DOI: 10.1016/S0040-4020(01)89827-6
Tetrahedron Letters, 23, p. 957, 1982 DOI: 10.1016/S0040-4039(00)86993-2
General Description
Reactions of the phosphinidene-bridged complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) with 3,5-di-tert-butyl-o-benzoquinone has been reported.
Purification Methods
It can be recrystallised from MeOH or pet ether, and forms fine red plates or rhombs. [Flaig et al. Justus Liebigs Ann Chem 597 196 1955, IR: Ley & Müller Chem Ber 89 1402 1956, Beilstein 7 IV 2113.]
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3,5-DI-TERT-BUTYL-O-BENZOQUINONE(3383-21-9)Related Product Information
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- TRANS-2-METHYL-1,3-PENTADIENE
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- TRANS-3-OCTENE
- 5-Methyl-2-hexanone
- 3-HEXENAL
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- 2,3,3-TRIMETHYL-1-BUTENE
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- 5-METHYL-2,3-HEXANEDIONE
- trans-2-Pentenal
- TRANS-4,4-DIMETHYL-2-PENTENE
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