Borane ammonia complex Chemical Properties

Melting point:

111-114 °C

storage temp. 

2-8°C

solubility 

DMSO (Slightly), Methanol (Slightly)

form 

Solid

color 

White to Off-White

Stability:

Explosive. Heating may cause explosion. Hygroscopic. Incompatible with acids, strong oxidizing agents.

InChI

InChI=1S/BH3.H3N/h2*1H3

InChIKey

WZMUUWMLOCZETI-UHFFFAOYSA-N

SMILES

B.N

Safety Information

Risk Statements 

5

Safety Statements 

14-15-36/37/39-26

RIDADR 

3191

WGK Germany 

3

F 

3-10

HazardClass 

4.2

PackingGroup 

II

HS Code 

28530090

Storage Class

11 - Combustible Solids

MSDS

• Language:English Provider:SigmaAldrich

Borane ammonia complex Usage And Synthesis

Chemical Properties

Borane ammonia complex is white powder or flakes

Uses

Borazane acts as a mild, efficient, and stereoselective reducing agent for aldehydes and ketones in protic or nonprotic media.It can be used as a storage medium for release of hydrogenBorazane is popularly used as an ammonia borane (AB) source for the formation of hexagonal boron nitride monolayers which are used as a substrate for graphene growth.

Uses

Borane ammonia complex is a proposed storage medium for hydrogen in motor fuel vehicles, also used in organic synthesis.

General Description

This product has been enhanced for energy efficiency.

reaction suitability

reagent type: reductant

Synthesis

Ammonia was bubbled through 30 ml of dimethylaniline borane (containing 70 mmol of borane) in 30 ml of toluene until all dimethylaniline was consumed. The reaction was monitored by 11B NMR spectroscopy. Removal of dimethylaniline and toluene was then carried out by filtration of the white solid ammonia borane, which was washed three times with toluene. The product was dried under vacuum.

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