4,4'-DIMETHOXYDIPHENYLAMINE Chemical Properties

Melting point:

101-102°C

Boiling point:

371.18°C (rough estimate)

Density 

1.0955 (rough estimate)

refractive index 

1.5300 (estimate)

storage temp. 

Keep in dark place,Inert atmosphere,Room temperature

solubility 

Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)

form 

Solid

pka

2.16±0.40(Predicted)

color 

Off-White to Light Brown

Water Solubility 

Soluble in methanol. Insoluble in water.

Sensitive 

Air Sensitive

BRN 

2214262

Stability:

Stability Combustible. Incompatible with strong oxidizing agents.

InChIKey

VCOONNWIINSFBA-UHFFFAOYSA-N

CAS DataBase Reference

101-70-2(CAS DataBase Reference)

NIST Chemistry Reference

Di-(4-methoxy phenyl) amine(101-70-2)

EPA Substance Registry System

4,4'-Dimethoxydiphenylamine (101-70-2)

Safety Information

Hazard Codes 

Xn

Risk Statements 

68-40-36/37/38

Safety Statements 

22-36/37/39-36/37-26-53

WGK Germany 

3

RTECS 

DU9085000

TSCA 

Yes

HS Code 

29222990

Toxicity

mouse,LD50,oral,2500mg/kg (2500mg/kg),BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)BEHAVIORAL: TREMORLUNGS, THORAX, OR RESPIRATION: OTHER CHANGES,Kauchuk i Rezina. Crude and Vulcanized Rubber. Vol. 26(9), Pg. 28, 1967.

MSDS

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4,4'-DIMETHOXYDIPHENYLAMINE Usage And Synthesis

Chemical Properties

silver-grey crystalline solid

Uses

4,4'-Dimethoxydiphenylamine is a diphenylamine derivative used as a chemical additive for cured rubber. It is used in the synthesis of amine electron donating groups in organic donor-bridge-acceptor dyads in Dye Sensitized Solar Cells (DSSC). 4,4?-Dimethoxydiphenylamine is an electron donor and used in the synthesis of organic nonlinear optical (NLO) chromophores which exhibit high thermal and chemical stability, high degree of non-linearity and transparency. They are used in high performance photonic devices.

Uses

4,4'-Dimethoxydiphenylamine is a diphenylamine derivative used as a chemical additive for cured rubber. 4,4'-Dimethoxydiphenylamine is highly toxic and may potentially induce chromosome abberation.

General Description

Fine very light gray to silver-gray crystalline solid.

Air & Water Reactions

4,4'-DIMETHOXYDIPHENYLAMINE may be sensitive to prolonged exposure to air. Slowly oxidized. Insoluble in water.

Reactivity Profile

4,4'-DIMETHOXYDIPHENYLAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

ACUTE/CHRONIC HAZARDS: 4,4'-DIMETHOXYDIPHENYLAMINE can produce extremely irritating fumes when exposed to air or fire.

Fire Hazard

Flash point data for 4,4'-DIMETHOXYDIPHENYLAMINE are not available. 4,4'-DIMETHOXYDIPHENYLAMINE is probably combustible.

4,4'-DIMETHOXYDIPHENYLAMINE(101-70-2)Related Product Information

• 4,4'-DIMETHOXYBENZHYDRYLAMINE
• tert-Butylchlorodiphenylsilane
• (Diacetoxyiodo)benzene
• Glycine
• Acid chloride
• n-Butyllithium
• Formic acid
• Boric acid
• Phosphomolybdic Acid
• L-Phenylalanine
• Sodium sulfide
• N,N-Diphenyl-p-phenylenediamine
• BIS(4-METHOXYBENZYL)AMINE HCL SALT
• BIS-(4-METHOXY-BENZYL)-AMINE
• BIS(4-METHOXYPHENYL)PHENYLPHOSPHINE
• bis(p-methoxyphenyl)iodonium bromide
• 4,4-DIMETHOXYDIPHENYLMETHANE
• BIS(4-METHOXYPHENYL) DISULPHIDE