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Methyl o-toluate

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Methyl o-toluate Basic information

Product Name:
Methyl o-toluate
Synonyms:
  • O-TOLUIC ACID METHYL ESTER
  • RARECHEM AL BF 0047
  • 2-METHYLBENZOIC ACID METHYL ESTER
  • 2-METHYL METHYLBENZOATE
  • METHYL-O-METHYL BENZOATE
  • METHYL O-TOLUATE
  • METHYL 2-TOLUATE
  • METHYL 2-METHYLBENZOATE
CAS:
89-71-4
MF:
C9H10O2
MW:
150.17
EINECS:
201-932-2
Product Categories:
  • Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • Chemical Synthesis
  • Esters
  • Organic Building Blocks
  • CARBOXYLICESTER
  • Aromatic Esters
  • bc0001
Mol File:
89-71-4.mol
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Methyl o-toluate Chemical Properties

Melting point:
<-50 °C
Boiling point:
207-208 °C (lit.)
Density 
1.073 g/mL at 25 °C (lit.)
vapor pressure 
12.9Pa at 23℃
refractive index 
1.518-1.52
Flash point:
82 °C
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
color 
Clear colorless
Odor
at 100.00 %. floral ylang orangeflower grape
Odor Type
floral
Water Solubility 
Not miscible or difficult to mix in water.
BRN 
2041846
InChIKey
WVWZECQNFWFVFW-UHFFFAOYSA-N
LogP
3 at 25℃
CAS DataBase Reference
89-71-4(CAS DataBase Reference)
NIST Chemistry Reference
Benzoic acid, 2-methyl-, methyl ester(89-71-4)
EPA Substance Registry System
Benzoic acid, 2-methyl-, methyl ester (89-71-4)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-36
WGK Germany 
3
TSCA 
Yes
HazardClass 
IRRITANT
HS Code 
29163990

MSDS

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Methyl o-toluate Usage And Synthesis

Chemical Properties

clear colorless liquid

Uses

It has been used in the preparation of 2-(azidomethyl)benzoic acid.

Synthesis Reference(s)

Chemistry Letters, 15, p. 851, 1986
Tetrahedron Letters, 24, p. 5181, 1983 DOI: 10.1016/S0040-4039(00)88391-4

General Description

Efficiency of reduction of methyl 2-methylbenzoate using different heterogeneous systems has been compared.

Flammability and Explosibility

Non flammable

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