ChemicalBook > Product Catalog > Inorganic chemistry > Inorganic salts > Metal halide and Halogen salt > Metal fluoride and salt > BISMUTH(III) FLUORIDE
BISMUTH(III) FLUORIDE
BISMUTH(III) FLUORIDE Basic information
- Product Name:
- BISMUTH(III) FLUORIDE
- Synonyms:
-
- BISMUTH(III) FLUORIDE
- BISMUTH FLUORIDE
- BISMUTH(III) TRIFLUORIDE
- BISMUTH TRIFLUORIDE
- Bismuthine, trifluoro-
- trifluoro-bismuthin
- trifluoro-Bismuthine
- Bismuth(III) fluoride anhydrous
- CAS:
- 7787-61-3
- MF:
- BiF3
- MW:
- 265.98
- EINECS:
- 232-124-8
- Product Categories:
-
- metal halide
- Bismuth Salts
- BismuthMetal and Ceramic Science
- Catalysis and Inorganic Chemistry
- Chemical Synthesis
- Crystal Grade Inorganics
- Salts
- Mol File:
- 7787-61-3.mol
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BISMUTH(III) FLUORIDE Chemical Properties
- Melting point:
- 727 °C
- Boiling point:
- 900°C
- Density
- 8.3 g/mL at 25 °C(lit.)
- refractive index
- 1.74
- solubility
- H2O: insoluble(lit.)
- form
- Powder
- Specific Gravity
- 5.32
- color
- white-gray cubic crystals, crystalline
- Water Solubility
- Insoluble in water. Soluble in HF.
- Crystal Structure
- YF3 type
- Sensitive
- Hygroscopic
- Merck
- 14,1265
- crystal system
- Nogata
- Space group
- Pnma
- Lattice constant
a/nm b/nm c/nm α/o β/o γ/o V/nm3 0.656 0.702 0.484 90 90 90 0.2228 - Exposure limits
- ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3 - CAS DataBase Reference
- 7787-61-3(CAS DataBase Reference)
- EPA Substance Registry System
- Bismuthine, trifluoro- (7787-61-3)
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Safety Information
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3260 8/PG 2
- WGK Germany
- 3
- F
- 10-21
- Hazard Note
- Corrosive
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 28261990
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
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BISMUTH(III) FLUORIDE Usage And Synthesis
Chemical Properties
White Crystal or crystalline powder
Physical properties
Bismuth fluoride is a heavy, white (gray if impure) crystalline powder, practically insoluble in water. M.p. 725-730°C; d. 8.3. Cubic (dimorphous).
Uses
Bismuth fluoride is used in the manufacturing of bismuth pentafluoride. It is an attractive reagent and catalyst in organic synthesis owing to its low cost, and ease of handling. It is also used in polarography.
Uses
In the preparation of bismuth pentafluoride, q.v.
Preparation
The preparation method of Bismuth fluoride: Freshly precipitated bismuth hydroxide is evaporated to dryness several times in a Pt dish, using an excess of hydrofluoric acid. It is then calcined in a covered Pt crucible until the HF has completely evaporated.
BISMUTH(III) FLUORIDESupplier
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
- market03@meryer.com
3B Pharmachem (Wuhan) International Co.,Ltd.
- Tel
- 821-50328103-801 18930552037
- 3bsc@sina.com
Alfa Aesar
- Tel
- 400-6106006
- saleschina@alfa-asia.com
Energy Chemical
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
Shanghai Hanhong Scientific Co.,Ltd.
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
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BISMUTH(III) FLUORIDE(7787-61-3)Related Product Information
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