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Diacetoxydimethylsilane

Basic information Features Safety Supplier Related

Diacetoxydimethylsilane Basic information

Product Name:
Diacetoxydimethylsilane
Synonyms:
  • (Acetyloxy)(dimethyl)silyl acetate
  • Dimethyldiacetoxysilicane
  • dimethyl-silanediodiacetate
  • Dimethylsilanediol, diacetate
  • Silanediol,dimethyl-,diacetate
  • LABOTEST-BB LT01406985
  • DIACETOXYDIMETHYLSILANE
  • DIMETHYLDIACETOXYSILANE
CAS:
2182-66-3
MF:
C6H12O4Si
MW:
176.24
EINECS:
218-562-2
Product Categories:
  • Crosslinkers
  • Crosslinking Agents
  • Functional Materials
  • Si (Classes of Silicon Compounds)
  • Silane Coupling Agents
  • Silane Coupling Agents (Intermediates)
  • Silyl Esters
  • Si-O Compounds
  • Acetoxy Silanes
Mol File:
2182-66-3.mol
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Diacetoxydimethylsilane Chemical Properties

Melting point:
-12.5 °C (lit.)
Boiling point:
163 °C (lit.)
Density 
1.054 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.403(lit.)
Flash point:
153 °F
form 
liquid
Specific Gravity
1.054
color 
Colorless to Light yellow to Light red
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
BRN 
1769843
CAS DataBase Reference
2182-66-3(CAS DataBase Reference)
NIST Chemistry Reference
Silanediol, dimethyl-, diacetate(2182-66-3)
EPA Substance Registry System
Silanediol, dimethyl-, diacetate (2182-66-3)
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Safety Information

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-28-36/37/39-45
RIDADR 
UN 3265 8/PG 3
WGK Germany 
3
10-21
TSCA 
Yes
HazardClass 
3.2
PackingGroup 
III
HS Code 
29319090

MSDS

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Diacetoxydimethylsilane Usage And Synthesis

Features

Dimethyldiacetoxysilane is a clear to yellowish liquid with acrid odor of acetic acid (vinegar). It hydrolyzes in the presence of moisture (acetic acid is released) to form silanols, which can react with themselves to pro-duce siloxanes or bind to inorganic substrates.
Acetoxy silanes are more reactive than alkoxysilanes. Acetoxy silanes are frequently used as one-component mixtures to make RTV-1 silicone sealants. These mixtures have an excess of multi-functional acetoxy silane added to silanol-terminated PDMS, which results in a PDMS chain with acetoxy groups at the ends. When this compound is exposed to moisture some acetoxy groups are hydrolyzed and self-condense or react with other acetoxy and rapid crosslinking takes place. Acetic acid formation is one of the driving forces of this reaction.

Chemical Properties

Colorless or yellowish transparent liquid

DiacetoxydimethylsilaneSupplier

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