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NITROMETHYL PHENYL SULFONE

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NITROMETHYL PHENYL SULFONE Basic information

Product Name:
NITROMETHYL PHENYL SULFONE
Synonyms:
  • BENZENESULPHONYL NITROMETHANE
  • BENZENESULFONYLNITROMETHANE
  • 4-BENZENESULPHONYLNITROMETHANE
  • TIMTEC-BB SBB003532
  • (NITROMETHYL)(DIOXO)PHENYL-LAMBDA6-SULFANE
  • NITROMETHYL PHENYL SULFONE
  • (NITROMETHYLSULFONYL)BENZENE
  • (PHENYLSULFONYL)NITROMETHANE
CAS:
21272-85-5
MF:
C7H7NO4S
MW:
201.2
EINECS:
244-308-5
Mol File:
21272-85-5.mol
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NITROMETHYL PHENYL SULFONE Chemical Properties

Melting point:
78-80 °C
Boiling point:
122-123 °C
Density 
1.397±0.06 g/cm3(Predicted)
pka
4.07±0.29(Predicted)
BRN 
1876502
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Safety Information

Hazard Codes 
Xi
Risk Statements 
20/21/22
Safety Statements 
22-24/25
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
2930909899

MSDS

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NITROMETHYL PHENYL SULFONE Usage And Synthesis

Purification Methods

Recrystallise the sulfone from CHCl3, or 95% EtOH, then sublime it at 100-120o/0.1 Torr and recrystallise again. It is an acidic analogue of nitromethane used for the general synthesis of aliphatic acids and nitriles and in cycloaddition reactions with olefins to form heterocycles. [Wade et al. J Org Chem 46 765 1981, 49 4595 1984, Beilstein 6 II 292.]

NITROMETHYL PHENYL SULFONESupplier

Energy Chemical
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Sigma-Aldrich
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