CYCLOPENTADIENYLMANGANESE TRICARBONYL
CYCLOPENTADIENYLMANGANESE TRICARBONYL Basic information
- Product Name:
- CYCLOPENTADIENYLMANGANESE TRICARBONYL
- Synonyms:
-
- CYCLOPENTADIENYLMANGANESE TRICARBONYL
- CYCLOPENTADIENYLTRICARBONYLMANGANESE
- tricarbonyl(eta-cyclopentadienyl)manganese
- Cyclopentadienyl marganese tricarbonyl
- Cyclopentadienylmanganesetricarbonyl,98%
- Manganese, tricarbonyl(.eta.5-2,4-cyclopentadien-1-yl)-
- cyclopentadienylmanganese(i) tricarbonyl
- (eta5-Cyclopentadienyl) manganese tricarbonyl
- CAS:
- 12079-65-1
- MF:
- C8H5MnO35*
- MW:
- 204.06
- EINECS:
- 235-142-4
- Product Categories:
-
- OIL ADDITIVE
- OCTANE BOOSTER
- ManganeseVapor Deposition Precursors
- Catalysis and Inorganic Chemistry
- Chemical Synthesis
- metallocene
- Manganese
- Precursors by Metal
- Mol File:
- 12079-65-1.mol
CYCLOPENTADIENYLMANGANESE TRICARBONYL Chemical Properties
- Melting point:
- 72-76 °C(lit.)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- crystal
- color
- yellow
- Water Solubility
- Soluble in water (70 ppm (25C)
- Sensitive
- Air Sensitive
- Exposure limits
- ACGIH: TWA 0.1 mg/m3 (Skin)
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 0.1 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3 - EPA Substance Registry System
- Manganese cyclopentadienyl tricarbonyl (12079-65-1)
Safety Information
- Hazard Codes
- T+
- Risk Statements
- 28
- Safety Statements
- 28-36/37-45
- RIDADR
- UN 2811 6.1/PG 2
- WGK Germany
- 3
- RTECS
- OO9720000
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- II
- HS Code
- 29310099
- Hazardous Substances Data
- 12079-65-1(Hazardous Substances Data)
- Toxicity
- mouse,LD50,intravenous,710ug/kg (0.71mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#11285,
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
CYCLOPENTADIENYLMANGANESE TRICARBONYL Usage And Synthesis
Chemical Properties
yellow crystals or crystalline chunks
Uses
Antiknock agent.
Uses
Octane enhancer for gasoline
Uses
Cyclopentadienylmanganese tricarbonyl is an important raw material and intermediate used in organic synthesis, pharmaceutical intermediates.
General Description
Bright yellow, crystalline solid with a camphor-like odor. Sublimes 75-77°C. Slightly soluble in water. Used as an octane enhancement additive for unleaded gasoline.
Reactivity Profile
MANGANESE CYCLOPENTAHIENYL TRICARBONYL is combustible. Heating causes evolution of carbon monoxide and other toxic or irritating gases. Heating in a confined space causes a rise in pressure with the risk of bursting. Incompatible with oxygen.
Hazard
Toxic material absorbed by skin. Central nervous system impairment and skin irritant.
Health Hazard
Manganese cyclopentadienyl tricarbonyl (MCT) causes convulsions and pulmonary edema in laboratory animals.
Safety Profile
A poison by ingestion, inhalation, intraperitoneal, and intravenous routes. A mild narcotic which can damage kidneys. When heated to decomposition it emits acrid smoke and irritating fumes. See also MANGANESE COMPOUNDS and CARBON MONOXIDE.
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