n-Tridecane
n-Tridecane Basic information
- Product Name:
- n-Tridecane
- Synonyms:
-
- N-TRIDECANE MIN. 99,9 % FOR GAS CHROMATO GRAPHY
- N-Tridecane>99%
- N-Tridecane~98%
- standardmaterial
- Tridecan
- TRIDECANE,N-(SG)
- 1-TRIDECANE
- NAPHTHOCAINE
- CAS:
- 629-50-5
- MF:
- C13H28
- MW:
- 184.36
- EINECS:
- 211-093-4
- Product Categories:
-
- Chemical Class
- Analytical Chemistry
- n-Paraffins (GC Standard)
- Standard Materials for GC
- Acyclic
- Alkanes
- Organic Building Blocks
- Hydrocarbons
- NeatsAlphabetic
- TP - TZ
- Alpha Sort
- NeatsVolatiles/ Semivolatiles
- T-ZAlphabetic
- Mol File:
- 629-50-5.mol
n-Tridecane Chemical Properties
- Melting point:
- -6--4 °C (lit.)
- Boiling point:
- 110-112 °C/12 mmHg (lit.) 234 °C (lit.)
- Density
- 0.756 g/mL at 25 °C (lit.)
- vapor density
- 6.4 (vs air)
- vapor pressure
- 1 mm Hg ( 59.4 °C)
- refractive index
- n20/D 1.425(lit.)
- Flash point:
- 215 °F
- storage temp.
- Store below +30°C.
- form
- Liquid
- color
- Clear colorless
- explosive limit
- 0.6-6.5%(V)
- Water Solubility
- PRACTICALLY INSOLUBLE
- BRN
- 1733089
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- InChIKey
- IIYFAKIEWZDVMP-UHFFFAOYSA-N
- LogP
- 7.331 (est)
- CAS DataBase Reference
- 629-50-5(CAS DataBase Reference)
- NIST Chemistry Reference
- Tridecane(629-50-5)
- EPA Substance Registry System
- Tridecane (629-50-5)
Safety Information
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-66-65
- Safety Statements
- 26-36-24/25-62
- WGK Germany
- 3
- RTECS
- YD3025000
- Autoignition Temperature
- >204 °C
- TSCA
- Yes
- HS Code
- 29011090
- Hazardous Substances Data
- 629-50-5(Hazardous Substances Data)
- Toxicity
- LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rat > 2000 mg/kg
MSDS
- Language:English Provider:n-Tridecane
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
n-Tridecane Usage And Synthesis
Chemical Properties
colourless liquid
Uses
Organic synthesis, distillation chaser.
Uses
n-Tridecane is used as a distillation chaser. It is a component of various fuels and solvents used in industry.
Definition
ChEBI: Tridecane is a straight chain alkane containing 13 carbon atoms. It forms a component of the essential oils isolated from plants such as Abelmoschus esculentus. It has a role as a plant metabolite and a volatile oil component.
Synthesis Reference(s)
The Journal of Organic Chemistry, 46, p. 3909, 1981 DOI: 10.1021/jo00332a030
Tetrahedron, 48, p. 8253, 1992 DOI: 10.1016/S0040-4020(01)80493-2
General Description
An oily straw yellow clear liquid with a hydrocarbon odor. Flash point 190-196°F. Specific gravity 0.76. Boiling point 456°F. Repeated or prolonged skin contact may irritate or redden skin, progressing to dermatitis. Exposure to high concentrations of vapor may result in headache and stupor.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Saturated aliphatic hydrocarbons, such as n-Tridecane, may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, they burn exothermically to produce carbon dioxide and water.
Health Hazard
May be harmful by inhalation, ingestion or skin absorption. Vapor or mist is irritating to the eyes, mucous membrane and upper respiratory tract. Causes skin irritation.
Safety Profile
Moderately toxic by intravenousroute. When heated to decomposition it emits acrid smokeand irritating fumes.
Carcinogenicity
Mice treated with tridecane developed tumors on their backs, after exposure to ultraviolet radiation at wavelengths longer than 350 nm, generally considered noncarcinogenic.
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n-Tridecane(629-50-5)Related Product Information
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- Triethylamine
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- Tridecane