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2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine

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2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine Basic information

Product Name:
2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine
Synonyms:
  • 2,4-bis(Trichloromethyl)-6-p-methoxystyryl-s-triazine
  • 3,5-Triazine,2-[2-(4-methoxyphenyl)ethenyl]-4,6-bis(trichloromethyl)-1
  • 5-triazine,2-[2-(4-methoxyphenyl)ethenyl]-4,6-bis(trichloromethyl)-3
  • PINA(R) PHOTO ADDITIVE TRIAZINE MOP
  • 2-(p-methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine
  • 2-(4-METHOXYSTYRYL)-4,6-BIS (TRICHLOROME
  • 2-[2-(4-Methoxyphenyl)ethenyl]-4,6-bis(trichloromethyl)-1,3,5-triazine
  • 4,6-Bis-(trichloromethyl)-2-(4-methoxystyryl)-1,3,5-triazine
CAS:
42573-57-9
MF:
C14H9Cl6N3O
MW:
447.96
EINECS:
255-893-1
Product Categories:
  • Cationic PhotoinitiatorsSelf Assembly&Contact Printing
  • Organic Photoinitiators
  • Photoacid Generators (PAGs)
  • Photoresists
  • Polymerization Initiators
Mol File:
42573-57-9.mol
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2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine Chemical Properties

Melting point:
192-195 °C (lit.)
Boiling point:
511.4±60.0 °C(Predicted)
Density 
1.605
pka
-1.88±0.10(Predicted)
form 
powder to crystal
color 
Light yellow to Amber to Dark green
InChI
InChI=1S/C14H9Cl6N3O/c1-24-9-5-2-8(3-6-9)4-7-10-21-11(13(15,16)17)23-12(22-10)14(18,19)20/h2-7H,1H3
InChIKey
MCNPOZMLKGDJGP-UHFFFAOYSA-N
SMILES
N1=C(C(Cl)(Cl)Cl)N=C(C(Cl)(Cl)Cl)N=C1C=CC1=CC=C(OC)C=C1
EPA Substance Registry System
1,3,5-Triazine, 2-[2-(4-methoxyphenyl)ethenyl]-4,6-bis(trichloromethyl)- (42573-57-9)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29336990

MSDS

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2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine Usage And Synthesis

Uses

Cationic photoinitiator. Nonionic photoacid generator.

Properties and Applications

2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine (R–Cl) appears as a versatile high-performance photoinitiator (PI) under LED exposure at 385, 395, or 405 nm (intensities in the range ~9–140 mW cm?2). It can be used as an efficient Type I cleavable photoinitiator for free radical polymerization of (meth)acrylates upon LED (e.g., 405 nm) exposure. Its high FRP photoinitiation ability under air demonstrates its capability to reduce the oxygen inhibition effect. Moreover, the R–Cl/amine (or R–Cl/N-vinylcarbazole) two-component system exhibits a higher photoinitiation ability than R–Cl alone in some cases. R–Cl/Iod/NVK is also efficient for the cationic photopolymerization of epoxides, especially at 405 nm[1].

References

[1] Zhang, Jing et al. “A known photoinitiator for a novel technology: 2-(4-methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine for near UV or visible LED?.” Polymer Chemistry 20 (2014): 6019–6026.

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