Isophthalic acid Chemical Properties

Melting point:

341-343 °C (lit.)

Boiling point:

214.32°C (rough estimate)

Density 

1,54 g/cm³

vapor pressure 

0Pa at 25℃

refractive index 

1.5100 (estimate)

storage temp. 

Sealed in dry,Room Temperature

solubility 

0.12g/l

form 

Crystalline Powder

pka

3.54(at 25℃)

color 

White to off-white

PH

3.33(1 mM solution);2.76(10 mM solution);2.24(100 mM solution)

Water Solubility 

0.01 g/100 mL (25 ºC)

Merck 

14,5197

BRN 

1909332

Dielectric constant

1.4（Ambient）

Stability:

Stable. Incompatible with strong oxidizing agents, strong bases.

InChIKey

QQVIHTHCMHWDBS-UHFFFAOYSA-N

LogP

1.66 at 25℃

CAS DataBase Reference

121-91-5(CAS DataBase Reference)

NIST Chemistry Reference

1,3-Benzenedicarboxylic acid(121-91-5)

EPA Substance Registry System

Isophthalic acid (121-91-5)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

24/25-36-26

WGK Germany 

2

RTECS 

NT2007000

Autoignition Temperature

1198 °F

TSCA 

Yes

HS Code 

29173980

Hazardous Substances Data

121-91-5(Hazardous Substances Data)

MSDS

• Language:English Provider:1,3-Benzenedicarboxylic acid
• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

Isophthalic acid Usage And Synthesis

Description

Isophthalic acid is an organic compound with the formula C₆H₄(CO₂H)₂. This colourless solid is an isomer of phthalic acid and terephthalic acid. These aromatic dicarboxylic acids are used as precursors (in form of acyl chlorides) to commercially important polymers, e.g. the fire-resistant material Nomex. Mixed with terephthalic acid, iso phthalic acid is used in the production of resins for drink bottles. The high-performance polymer poly benzimidazole is produced from iso phthalic acid.

Chemical Properties

Isophthalic acid is a white crystalline powder or needle-like crystals and it’s an isomer of phthalic acid and terephthalic acid.It is insoluble in cold water but soluble in oxygenated solvents and alcohol. It is combustible and finely dispersed particles will form explosive mixtures in air.

Isophthalic Acid (PIA) is mainly used in the production of bottle PET, also used in the production of alkyd resin, polyester resin, also used in the production of photosensitive materials, pharmaceutical intermediates and so on.
One of the largest applications for PIA is in unsaturated polyester resins for high-quality gel coats. The hardness, stain and detergent resistance characteristics of PIA are ideal for polyester solid-surface countertops that are an inexpensive alternative to acrylics.

Uses

Isophthalic acid is used as an intermediate for high performance unsaturated polyesters, resins for coatings, high solids paints, gel coats and modifier of polyethylene terephthalate for bottles. It acts as precursors for the fire-resistant material nomex as well as used in the preparation of high-performance polymer polybenzimidazole. It is also employed as an input for the production of insulation materials.

Uses

Purified Isophthalic Acid (PIA) is mainly used as intermediate for high performance UPR, resins for coatings, high solids paints, gel coats, modifier of PET for bottles. Product Data Sheet

Definition

ChEBI: A benzenedicarboxylic acid that is benzene substituted by carboxy groups at position 1 and 3. One of three possible isomers of benzenedicarboxylic acid, the others being phthalic and terephthalic acids.

Preparation

Iso phthalic acid is produced on the billion kilogram per year scale by oxidizing meta-xylene using oxygen . The process employs a cobalt-manganese catalyst. In the laboratory, chromic acid can be used as the oxidant. It also arises by fusing potassium meta-sulpho benzoate , or meta - brom benzoate with potassium formate (terephthalic acid is also formed in the last case).
The barium salt (as its hexa hydrate) is very soluble (a distinction between phthalic and terephthalic acids). Uvitic acid, 5- methylisophthalic acid, is obtained by oxidizing mesitylene or by condensing pyroracemic acid with baryta water.

Synthesis Reference(s)

Journal of the American Chemical Society, 82, p. 1911, 1960 DOI: 10.1021/ja01493a020

General Description

White solid with a slight unpleasant odor. Sinks in water.

Air & Water Reactions

Dust forms explosive mixture in air [USCG, 1999].

Reactivity Profile

Isophthalic acid is a carboxylic acid. Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in Isophthalic acid to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.

Health Hazard

May cause slight to moderate irritation of eyes, skin, and mucous membranes on prolonged contact. Ingestion may cause gastrointestinal irritation.

Fire Hazard

Behavior in Fire: Dust forms explosive mixture in air.

Flammability and Explosibility

Non flammable

Purification Methods

Crystallise the acid from aqueous EtOH. [Beilstein 9 IV 3292.]

Isophthalic acid(121-91-5)Related Product Information

• 3-(Trifluoromethyl)cinnamic acid
• Folic acid
• Bis(2-ethylhexyl) phthalate
• 5-Hydroxyisophthalic acid
• Citric acid
• Ethyl 2-(Chlorosulfonyl)acetate
• Terephthalic acid
• Metaraminol bitartrate
• Phthalic acid
• Diethyl phthalate
• Benzyl butyl phthalate
• Dacthal
• Dimethyl isophthalate
• Diisobutyl phthalate
• Hyaluronic acid
• Potassium hydrogen phthalate
• 5-Aminoisophthalic acid
• Stearic acid