[Ir(dtbbpy)(ppy)2][PF6]
[Ir(dtbbpy)(ppy)2][PF6] Basic information
- Product Name:
- [Ir(dtbbpy)(ppy)2][PF6]
- Synonyms:
-
- [Ir(dtbbpy)(ppy)2][PF6]
- (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
- (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
- [Ir(dtbbpy)(ppy)
- Ir(ppy)2(dtbbpy)PF6
- (4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
- [4,4'-Bis(tert-butyl)-2,2'-bipyridine]bis[2-(2-pyridinyl)phenyl]iridium(III) hexafluorophosphate
- (4,4'-Di-tert-butyl-2,2'-bipyridine)di[(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate
- CAS:
- 676525-77-2
- MF:
- C40H40F6IrN4P
- MW:
- 913.97
- Mol File:
- 676525-77-2.mol
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[Ir(dtbbpy)(ppy)2][PF6] Chemical Properties
- storage temp.
- 2-8°C
- form
- crystal
- color
- yellow
- λmax
- 380nm(CH2Cl2)(lit.)
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[Ir(dtbbpy)(ppy)2][PF6] Usage And Synthesis
Reaction
- This Iridium catalyst is used in the synthesis of β-amidovinyl sulfones via visible-light photoredox catalysis.
- Numerous uses of this photoredox catalyst are reported
Uses
[Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:
- Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
- Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
- Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
- Aryl-alkyl C?C reductive cross-coupling reactions.
[Ir(dtbbpy)(ppy)2][PF6]Supplier
Shengyang Runze (Beijing) Technology Co., Gold
- Tel
- 010-010-57302162 17611011830
- lyt001@syrz01.com
Jiangsu Boquan Biotechnology Co., Ltd. Gold
- Tel
- 15252131412
- 5954981@qq.com
TCI (Shanghai) Development Co., Ltd.
- Tel
- 021-67121386
- Sales-CN@TCIchemicals.com
BeiJing Hwrk Chemicals Limted
- Tel
- 0757-86329057 18501085097
- sales3.gd@hwrkchemical.com
Energy Chemical
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
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[Ir(dtbbpy)(ppy)2][PF6](676525-77-2)Related Product Information
- Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate
- Ir[dFppy]2(dtbbpy)PF6
- hexafluorophosphate
- Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-)
- Ir[p-F(Me)ppy]2(dtbbpy)PF6
- Coumarin 30
- COUMARIN 152
- 7-DIETHYLAMINO-4-(TRIFLUOROMETHYL)COUMARIN
- Exciton Coumarin 545
- Coumarin 153
- (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate
- 2,6-bis(diphenylaMino)anthracene-9,10-dione
- Tris(2-phenylpyridine)iridium (Ir(ppy)3)
- Bis[2-(2-benzothiazoly)phenolato]zinc(II)
- N,N'- Dibutylquinacridone
- Coumarin 6
- COUMARIN 7
- Rhodamine B