Basic information Reaction Safety Supplier Related

[Ir(dtbbpy)(ppy)2][PF6]

Basic information Reaction Safety Supplier Related

[Ir(dtbbpy)(ppy)2][PF6] Basic information

Product Name:
[Ir(dtbbpy)(ppy)2][PF6]
Synonyms:
  • [Ir(dtbbpy)(ppy)2][PF6]
  • (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
  • (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
  • [Ir(dtbbpy)(ppy)
  • Ir(ppy)2(dtbbpy)PF6
  • (4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
  • [4,4'-Bis(tert-butyl)-2,2'-bipyridine]bis[2-(2-pyridinyl)phenyl]iridium(III) hexafluorophosphate
  • (4,4'-Di-tert-butyl-2,2'-bipyridine)di[(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate
CAS:
676525-77-2
MF:
C40H40F6IrN4P
MW:
913.97
Mol File:
676525-77-2.mol
More
Less

[Ir(dtbbpy)(ppy)2][PF6] Chemical Properties

storage temp. 
2-8°C
form 
crystal
color 
yellow
λmax
380nm(CH2Cl2)(lit.)
More
Less

Safety Information

Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
TSCA 
No
HS Code 
2843.90.0000
More
Less

[Ir(dtbbpy)(ppy)2][PF6] Usage And Synthesis

Reaction

  1. This Iridium catalyst is used in the synthesis of β-amidovinyl sulfones via visible-light photoredox catalysis.
  2. Numerous uses of this photoredox catalyst are reported

Uses

[Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:

  • Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
  • Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
  • Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
  • Aryl-alkyl C?C reductive cross-coupling reactions.

[Ir(dtbbpy)(ppy)2][PF6]Supplier

Shengyang Runze (Beijing) Technology Co., Gold
Tel
010-010-57302162 17611011830
Email
lyt001@syrz01.com
Jiangsu Boquan Biotechnology Co., Ltd. Gold
Tel
15252131412; 15252131412
Email
5954981@qq.com
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Email
Sales-CN@TCIchemicals.com
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Email
sales.bj@hwrkchemical.com
Energy Chemical
Tel
021-021-58432009 400-005-6266
Email
sales8178@energy-chemical.com